Thermomechanical characterisation and plane stress linear viscoelastic modelling of ethylene-tetra-fluoroethylene foils

IF 2.1 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Mechanics of Time-Dependent Materials Pub Date : 2024-08-28 DOI:10.1007/s11043-024-09704-5
Alessandro Comitti, Federico Bosi
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Abstract

Ethylene-tetra-fluoroethylene (ETFE) is a polymer employed in tension membrane structures with mechanical properties that strongly depend on time and temperature effects. A comprehensive understanding of the mutual influence of these variables and a unified viscoelastic constitutive model design can enable wider exploitation of ETFE in sustainable lightweight construction. This study presents a thermomechanical characterisation of ETFE foils through quasi-static tensile experiments spanning two orders of magnitude of strain rates, creep, relaxation, shear and dynamic cyclic tests in a wide range of temperatures suitable for building applications, from \(-20^{\circ }\text{ C}\) to \(60^{\circ }\text{ C}\). The experimental results in different material orientations are used to identify the limits of the linear viscoelastic domain, define the direction-dependent creep compliance master curves and calibrate the parameters of a plane stress orthotropic linear viscoelastic model, employing the Boltzmann superposition and the time-temperature superposition principles. The model has been numerically implemented using a recursive integration algorithm and its code is provided open source. A validation on independently acquired data shows the accuracy of the constitutive model in predicting ETFE behaviour within the linear viscoelastic regime usually adopted during structural design, with excellent extrapolation capabilities outside the range of the calibration data.

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乙烯-四氟乙烯箔的热力学特性和平面应力线性粘弹性建模
乙烯-四氟乙烯(ETFE)是一种用于张拉膜结构的聚合物,其机械性能与时间和温度效应密切相关。全面了解这些变量的相互影响并设计统一的粘弹性结构模型,可使 ETFE 在可持续轻质建筑中得到更广泛的应用。本研究通过准静态拉伸实验对 ETFE 薄膜进行了热力学表征,实验跨越了两个数量级的应变率、蠕变、松弛、剪切和动态循环测试,实验温度范围很广,从适合建筑应用的 -20^{circ }\text{ C}\ 到 60^{circ }\text{ C}\ 。不同材料方向上的实验结果被用来确定线性粘弹性域的极限,定义与方向相关的蠕变顺应性主曲线,并利用玻尔兹曼叠加和时间-温度叠加原理校准平面应力正交线性粘弹性模型的参数。该模型采用递归积分算法进行数值计算,其代码开源。对独立获取的数据进行的验证表明,该构成模型在预测结构设计中通常采用的线性粘弹性体系内的 ETFE 行为时非常准确,并且在校准数据范围之外具有出色的外推能力。
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来源期刊
Mechanics of Time-Dependent Materials
Mechanics of Time-Dependent Materials 工程技术-材料科学:表征与测试
CiteScore
4.90
自引率
8.00%
发文量
47
审稿时长
>12 weeks
期刊介绍: Mechanics of Time-Dependent Materials accepts contributions dealing with the time-dependent mechanical properties of solid polymers, metals, ceramics, concrete, wood, or their composites. It is recognized that certain materials can be in the melt state as function of temperature and/or pressure. Contributions concerned with fundamental issues relating to processing and melt-to-solid transition behaviour are welcome, as are contributions addressing time-dependent failure and fracture phenomena. Manuscripts addressing environmental issues will be considered if they relate to time-dependent mechanical properties. The journal promotes the transfer of knowledge between various disciplines that deal with the properties of time-dependent solid materials but approach these from different angles. Among these disciplines are: Mechanical Engineering, Aerospace Engineering, Chemical Engineering, Rheology, Materials Science, Polymer Physics, Design, and others.
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