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Fractional three-phase-lag thermoelastic modeling of a polymer nanoshell under ramp-type heating and electromagnetic coupling 斜坡式加热和电磁耦合下聚合物纳米壳的分数阶三相滞后热弹性建模
IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-12-08 DOI: 10.1007/s11043-025-09840-6
Wei Peng, Qingmeng Wu, Xu Zhang

With the rapid development and application of ultra-short pulses in the micro-machining of viscoelastic structures, the transient thermodynamic response at the micro/nano scale have become of great importance. Increasingly crucial at the microscale are the scale and memory effects in elastic deformation and heat transfer. A multitude of experimental and theoretical studies indicate that, for practical analyses, the thermal conductivity of materials ought not to be treated as a fixed value. This work aims to formulate a thermoviscoelastic model by incorporating a fractional-order three-phase-lag heat conduction model. The proposed framework utilizes the Atangana-Baleanu definition of fractional derivative, which features a non-singular kernel, along with an extended Caputo definition to describe the time-dependent characteristics of heat conduction. Additionally, the nonlocal elasticity model is taken into account in the stress-strain relationships. Then, the modified model is applied to investigate the nonlinear electro-magneto-thermo-viscoelastic response of a polymer spherical nanoshell with variable thermal conductivity subjected to ramp-type heating load under the effect of a magnetic field. Taking into account the variable thermal conductivity, the nonlinear governing equations are derived. Employed to derive and solve the governing equations are the Laplace and Kirchhoff transformations. In-depth discussions are carried out regarding the influences of diverse factors such as the fractional-order parameter, the nonlocal parameter and the variable thermal conductivity on physical quantities.

随着超短脉冲在粘弹性结构微加工中的迅速发展和应用,微纳尺度下的瞬态热力学响应变得非常重要。在微观尺度上,弹性变形和热传递中的尺度效应和记忆效应日益重要。大量的实验和理论研究表明,在实际分析中,材料的热导率不应被视为一个固定值。本工作旨在通过结合分数阶三相滞后热传导模型来制定热粘弹性模型。提出的框架利用分数阶导数的Atangana-Baleanu定义,其特征是非奇异核,以及扩展的Caputo定义来描述热传导的时间依赖特征。此外,在应力应变关系中考虑了非局部弹性模型。然后,应用修正后的模型研究了变导热聚合物球形纳米壳在磁场作用下斜坡式加热载荷下的非线性电-磁-热-粘弹性响应。考虑变导热系数,导出了非线性控制方程。用于推导和求解控制方程的是拉普拉斯变换和基尔霍夫变换。深入讨论了分数阶参数、非定域参数和变导热系数等多种因素对物理量的影响。
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引用次数: 0
High-throughput measurement of permanent strains in viscoelastic polymers 粘弹性聚合物中永久应变的高通量测量
IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-12-04 DOI: 10.1007/s11043-025-09845-1
Vivek Khare, Kawai Kwok

A high-throughput characterization scheme to determine yielding and permanent strain accumulation in polymers is presented. Measurement of permanent strains in polymers is challenging because of the extended duration associated with viscoelastic recovery, especially when tests need to be repeated under different loading histories. The proposed testing method can dramatically reduce the experimental efforts for long-term testing of time-dependent materials by producing a multitude of data from a single experiment. This is achieved by imposing a known stress gradient and employing a full-field strain measurement technique to obtain a series of creep curves under varying stress levels simultaneously. The method is demonstrated on low density polyethylene thin films used in superpressure balloons. Uniaxial creep-recovery tests are performed on polyethylene in two different material directions. Residual strains are measured after viscoelastic recovery to determine yielding and the subsequent evolution of permanent strain.

一个高通量的表征方案,以确定屈服和永久应变积累的聚合物提出。聚合物的永久应变测量具有挑战性,因为粘弹性恢复的持续时间较长,特别是当需要在不同的加载历史下重复测试时。所提出的测试方法可以通过单个实验产生大量数据,从而大大减少对时间依赖性材料进行长期测试的实验工作量。这是通过施加已知的应力梯度并采用全场应变测量技术同时获得不同应力水平下的一系列蠕变曲线来实现的。该方法在超压气球用低密度聚乙烯薄膜上得到了验证。对聚乙烯在两个不同的材料方向上进行了单轴蠕变恢复试验。粘弹性恢复后测量残余应变,以确定屈服和永久应变的后续演变。
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引用次数: 0
Degradation of recycled heterogeneous aggregate concrete with supplementary cementitious materials under sulfate erosion and dry - wet cycles 补充胶凝材料再生非均质骨料混凝土在硫酸盐侵蚀和干湿循环下的降解
IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-12-01 DOI: 10.1007/s11043-025-09844-2
Zequan Xu, Shiyuan Li, Huining Xu

The extensive use of materials in the construction industry imposes risks of depleting natural aggregates and increased carbon emissions, thereby motivating the search for sustainable alternatives. This work investigates the influence of supplementary cementitious materials (SCMs), including fly ash (FA), silica fume (SF), and ground-granulated blast-furnace slag (GBFS) on the durability and mechanical behavior of recycled heterogeneous aggregate concrete (RAC) subjected to sulfate erosion and dry–wet cycles (SEDWCs). Durability performance was evaluated through observation of surface appearance and mass variation, and digital image correlation (DIC) was used to monitor crack evolution and failure modes under uniaxial compression. Microscale mechanisms were examined using X-ray diffraction (XRD), scanning electron microscopy (SEM), and mercury intrusion porosimetry (MIP). Incorporating SCMs mitigated surface deterioration, stabilized mass change, and enhanced compressive strength. DIC observations revealed delayed crack initiation and less severe damage in SCM-modified RAC, with failure modes shifting from predominant shear to combined shear–cohesion failure. Microstructural analyses confirmed that SCMs densified the cement matrix and refined the interfacial transition zone (ITZ). Among the SCMs, silica fume exhibited the strongest resistance to SEDWCs, while fly ash and GBFS also improved durability compared with RAC without SCMs. These results demonstrate that the combined use of recycled aggregates and supplementary cementitious materials can significantly enhance the long-term performance of concrete in sulfate-rich cyclic environments, advancing the development of sustainable construction materials.

建筑行业中材料的广泛使用带来了消耗天然骨料和增加碳排放的风险,从而促使人们寻找可持续的替代品。本研究研究了补充胶凝材料(SCMs),包括粉煤灰(FA)、硅灰(SF)和磨粒高炉渣(GBFS)对再生非均质骨料混凝土(RAC)经受硫酸盐侵蚀和干湿循环(SEDWCs)的耐久性和力学行为的影响。通过观察表面形貌和质量变化来评估耐久性能,并采用数字图像相关(DIC)技术监测单轴压缩下的裂纹演化和破坏模式。采用x射线衍射(XRD)、扫描电镜(SEM)和汞侵入孔隙度测定(MIP)等方法对微尺度机理进行了研究。结合SCMs减轻了表面劣化,稳定了质量变化,并提高了抗压强度。DIC观察显示,sc -改性RAC的裂纹起裂延迟,破坏程度较轻,破坏模式从主要剪切破坏转变为剪切-粘聚联合破坏。微观结构分析证实,SCMs致密化了水泥基体,细化了界面过渡区(ITZ)。在SCMs中,硅灰对SEDWCs的抵抗力最强,而粉煤灰和GBFS与没有SCMs的RAC相比也提高了耐久性。研究结果表明,再生骨料与补充胶凝材料的结合使用可以显著提高混凝土在富硫酸盐循环环境中的长期性能,促进可持续建筑材料的发展。
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引用次数: 0
Synergistic effects of fin geometry and nanoparticle integration on melting enhancement in phase change material–based thermal energy storage 相变材料储热中翅片几何形状和纳米颗粒集成对熔融增强的协同效应
IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-11-24 DOI: 10.1007/s11043-025-09841-5
Hassan Waqas, Md. Jahid Hasan, Saima Zainab, Taseer Muhammad

Enhancing the melting rate of Phase Change Materials (PCMs) is critical for improving the efficiency of Thermal Energy Storage (TES) systems. Although optimized fin geometries have been widely studied, the combined role of nanoparticle-enhanced molten-salt PCMs with fins has received limited attention. A numerical investigation is conducted on the melting behavior of molten salt PCMs incorporated with Cu and TiO2 nanoparticles in a cylindrical TES unit featuring three fin geometries: longitudinal, Y-shaped, and tuning fork-shaped. Simulations are performed using ANSYS Fluent software and validated against published experimental data. The primary performance indicators, including the temperature distribution, velocity fields and liquid fraction, are analyzed. At a comparable melt fraction (∼97%), the addition of nanoparticles significantly reduced the melting time across all fin configurations, from 345 s to 192 s for longitudinal fins, from 244 s to 137 s for Y-shaped fins and from 202 s to 114 s for fork-shaped fins. These results demonstrate that nanoparticle integration accelerates the melting process by approximately 44-50%, with performance strongly dependent on the fin design. These findings indicate the synergistic benefits of fin geometry and nanoparticle additives, which provide practical guidelines for the design of high-efficiency TES devices.

提高相变材料(PCMs)的熔化速率对于提高热储能(TES)系统的效率至关重要。虽然优化鳍的几何形状已经得到了广泛的研究,但纳米颗粒增强熔融盐PCMs与鳍的结合作用却受到了有限的关注。本文对含Cu和TiO2纳米颗粒的熔盐PCMs在纵向、y形和叉形三种翅片结构的圆柱形TES单元中的熔化行为进行了数值研究。利用ANSYS Fluent软件进行了仿真,并根据已发表的实验数据进行了验证。分析了温度分布、速度场和液率等主要性能指标。在相当的熔体分数(~ 97%)下,纳米颗粒的加入显著缩短了所有鳍形的熔化时间,纵鳍从345秒减少到192秒,y形鳍从244秒减少到137秒,叉形鳍从202秒减少到114秒。这些结果表明,纳米颗粒集成加速了大约44-50%的熔化过程,其性能强烈依赖于鳍的设计。这些发现表明了翅片几何形状和纳米颗粒添加剂的协同效益,为高效TES器件的设计提供了实用指导。
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引用次数: 0
Non-similar analysis of ternary hybrid second-grade MHD nanofluid flow over linearly stretching sheet 三元混合二级MHD纳米流体在线性拉伸薄片上流动的非相似分析
IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-11-24 DOI: 10.1007/s11043-025-09842-4
Amara Bibi, Javeria Nawaz Abbasi

Effective heat transfer is crucial for engineering applications such as heat exchangers, electronics cooling, and HVAC systems. Moreover, this paper provides an extensive examination of the physical properties of viscoelastic liquids that are emerging in relation to important profiles, considering the copper oxide (left ( CuO right )), silver (left ( AgO right )), and zirconium dioxide (left ( Zr O_{2} right )), immersed in the base fluid ethylene glycol (EG). Viscous dissipation, porosity, and joule heating effects are introduced in the formulation of the problem. The differential equations are dimensionless after the mathematical formulations via a non-similarity conversion. The local non-similarity method transforms non-similar PDEs into ODEs, which are then solved numerically using MATLAB’s bvp4c. Important physical parameters are given in tabular form, such as skin friction and Nusselt values. The temperature distribution has been seen to increase when the viscoelastic parameter (second-grade fluid) increases. It is discovered that the findings converge more quickly and are validated for limited circumstances. Here are some key applications of the present work: industrial cooling systems, polymer processing, chemical engineering, biomedical engineering, heat exchangers, energy systems, cooling of microelectronic devices.

有效的传热对于热交换器、电子冷却和暖通空调系统等工程应用至关重要。此外,本文还对粘弹性液体的物理性质进行了广泛的研究,这些物理性质与重要的概况有关,考虑到氧化铜(left ( CuO right ))、银(left ( AgO right ))和二氧化锆(left ( Zr O_{2} right ))浸泡在基础流体乙二醇(EG)中。在问题的表述中引入了粘性耗散、孔隙和焦耳热效应。微分方程经非相似转换后为无因次方程。局部非相似法将非相似偏微分方程转化为偏微分方程,然后利用MATLAB的bvp4c进行数值求解。重要的物理参数以表格形式给出,如皮肤摩擦和努塞尔值。温度分布随粘弹性参数(二级流体)的增大而增大。研究发现,这些发现的收敛速度更快,并且在有限的情况下得到了验证。以下是目前工作的一些关键应用:工业冷却系统、聚合物加工、化学工程、生物医学工程、热交换器、能源系统、微电子器件的冷却。
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引用次数: 0
Comparison of energy absorption in negative stiffness honeycombs made of high-performance Polyamide 11 and 12 高性能聚酰胺11和聚酰胺12负刚度蜂窝的吸能比较
IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-11-10 DOI: 10.1007/s11043-025-09839-z
M. Shafipour, S. Y. Ahmadi-Brooghani

Negative stiffness honeycombs are energy absorbers that absorb energy by transitioning from one buckling mode to another, and their snap-through behaviour in cells. They have a fundamental property as an energy absorber; in this type of absorber, negative stiffness causes reversibility after impact. In this study, the effect of negative stiffness honeycomb material in increasing energy absorption is investigated experimentally and numerically. Quasi-static tests are performed on negative stiffness honeycombs made of polyamide 11 (PA11) and polyamide 12 (PA12). Then, the finite element (FE) model of the structure is simulated under quasi-static compression. The FE model requires the nonlinear elastic and viscoelastic properties of the materials used to make the honeycombs. For this purpose, tensile and stress relaxation tests are performed. The Prony series coefficients for polyamide materials 11 and 12 are extracted and used in the FE model. Next, the energy absorption performance of negative stiffness honeycombs of PA11 and PA12 is compared experimentally and numerically. The comparison shows that the energy absorption per unit mass (SEA) for a negative stiffness honeycomb made of PA11 is 1.7 times higher in the experimental data and 1.62 times higher in the FE result than negative stiffness honeycomb made of PA12. Other fundamental parameters of energy absorption also confirm the higher efficiency of negative stiffness honeycombs made of PA11. This study provides a unique contribution by integrating experimentally determined nonlinear viscoelastic properties into the FE model and offering a comparison of energy absorption performance between PA11 and PA12 in negative stiffness honeycombs.

负刚度蜂窝是一种能量吸收器,通过从一种屈曲模式过渡到另一种屈曲模式来吸收能量,以及它们在细胞中的断裂行为。它们具有吸收能量的基本特性;在这种类型的减震器中,负刚度导致碰撞后的可逆性。本文研究了负刚度蜂窝材料在提高能量吸收方面的作用。对聚酰胺11 (PA11)和聚酰胺12 (PA12)的负刚度蜂窝进行了准静态试验。然后,对结构在准静态压缩下的有限元模型进行了仿真。有限元模型需要蜂窝材料的非线性弹性和粘弹性特性。为此,进行拉伸和应力松弛试验。提取了聚酰胺材料11和12的proony级数系数,并将其用于有限元模型。其次,对PA11和PA12负刚度蜂窝的吸能性能进行了实验和数值比较。对比结果表明,PA11负刚度蜂窝的单位质量吸能(SEA)比PA12负刚度蜂窝高1.7倍,比PA12负刚度蜂窝高1.62倍。其他吸能基本参数也证实了PA11负刚度蜂窝具有较高的效率。该研究通过将实验确定的非线性粘弹性特性集成到有限元模型中,并提供了PA11和PA12在负刚度蜂窝中的能量吸收性能的比较,从而做出了独特的贡献。
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引用次数: 0
Tannic acid treatment of fine recycled concrete aggregates (RCAs) for better impact resistance performance of cementitious materials 单宁酸处理再生混凝土细骨料(RCAs)为抗冲击性能更好的胶凝材料
IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-11-10 DOI: 10.1007/s11043-025-09838-0
Liang Wang, Hongxin Xu, Jian Xu, Wenfeng Shen, Hao Wang, Yan Ge, Wenqing Cheng

Fine recycled concrete aggregate (RCA) exhibits inferior bonding properties with cement due to its high water absorption and porosity. Incorporating fine RCAs in cementitious materials leads to the significant reduction in dynamic mechanical performance. To address this issue, a compound inspired by tea stains, tannic acid (TA), is used to treat the fine RCAs. The results suggest that the width of the interface transition zone (ITZ) between fine RCA and the new matrix is significantly reduced after this treatment, indicating the improvement in bonding properties. Dynamic compression tests are conducted to examine the impact resistance performance of cement mortar containing fine RCAs through employing the Split Hopkinson Pressure Bar (SHPB) apparatus. When subjected to impact loads, mortars with treated fine RCAs indicate higher dynamic compressive strength and enhanced completeness. The dynamic compressive strength and total energy absorption exhibit the exponential positive correlation with the strain rate. The strain rate effect is more pronounced when the strain rate is below 100 s−1. Importantly, mortars with treated fine RCAs manifest superior total energy absorption, enabling them to absorb and dissipate more impact energy. The mortar containing fine RCAs treated with 0.5%TA reveals excellent impact resistance performance, surpassing even that of the cement mortar with natural fine aggregates. Moreover, 0.5%TA group shows better economic benefits than the plain mortar, indicating that the TA treatment method has good application prospects.

细再生混凝土骨料(RCA)由于吸水率和孔隙率高,与水泥的粘结性能较差。在胶凝材料中加入细小的rca会导致动态力学性能的显著降低。为了解决这个问题,一种受茶渍启发的化合物单宁酸(TA)被用来治疗细小的rca。结果表明,经此处理后,细RCA与新基体之间的界面过渡区(ITZ)宽度明显减小,表明键合性能得到改善。采用分离式霍普金森压杆(Split Hopkinson Pressure Bar, SHPB)试验装置,对含细RCAs水泥砂浆的抗冲击性能进行了动态试验研究。当受到冲击载荷时,经过处理的细rca砂浆具有更高的动态抗压强度和增强的完整性。动态抗压强度和总能量吸收与应变速率呈指数正相关。当应变速率小于100 s−1时,应变速率效应更为明显。重要的是,经过处理的细RCAs砂浆表现出优越的总能量吸收,使其能够吸收和消散更多的冲击能量。经0.5%TA处理的细骨料RCAs砂浆具有优异的抗冲击性能,甚至超过了天然细骨料水泥砂浆。0.5%TA组的经济效益优于普通砂浆,说明TA处理方法具有良好的应用前景。
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引用次数: 0
Causality of strain within framework of small and large amplitude oscillatory testing 大、小振幅振荡试验框架内应变的因果关系
IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-11-05 DOI: 10.1007/s11043-025-09837-1
Djema Amar, Bechir Hocine

The Small Amplitude Oscillatory Strain (SAOS) testing is commonly used to measure linear viscoelastic functions such as elastic moduli, which are denoted respectively (G^{*}(iomega )) and (E^{*}(iomega )) in simple shear and tension-compression. Beyond the linear regime, Large Amplitude Oscillatory Strain (LAOS) is a widely used experimental technique to investigate nonlinear phenomena. From mathematical standpoint, Fourier transform and Fourier series are used to handle SAOS and LAOS data. In general, SAOS-tests do not account a strain jump discontinuity to make easy measurement data processing. Thereby, we focus on the influence of a strain jump discontinuity (or not) on the response of the Cauchy stress. First, we investigate the problem of strain discontinuity (or not) within framework of one-dimensional isotropic linear viscoelasticity by considering both the integral approach and the fractional Maxwell constitutive model. Second, we assume that, the Large Amplitude Oscillations Strain (LAOS) is equivalent to small oscillations around a static pre-deformation. It means that, the jump at the origin is shifted to minus infinity in the time scale. Therefore, we investigate the first and third harmonics within framework of the nonlinear Kelvin-Voigt model. We conclude with some future perspectives for the present work.

小振幅振荡应变(SAOS)试验通常用于测量弹性模量等线性粘弹性函数,在简单剪切和拉压缩中分别表示(G^{*}(iomega ))和(E^{*}(iomega ))。大振幅振荡应变(Large Amplitude Oscillatory Strain, LAOS)是一种被广泛应用于研究非线性现象的实验技术。从数学角度出发,采用傅里叶变换和傅里叶级数来处理SAOS和LAOS数据。通常,saos测试不考虑应变跳变不连续,以便于测量数据的处理。因此,我们的重点是应变跳跃不连续(或不)对柯西应力响应的影响。首先,考虑积分方法和分数阶Maxwell本构模型,研究了一维各向同性线性粘弹性框架下的应变不连续问题。其次,我们假设,大振幅振荡应变(老挝)是等效的小振荡周围的静态预变形。这意味着,原点的跳跃在时间尺度上移到了负无穷。因此,我们研究了非线性Kelvin-Voigt模型框架内的一阶和三阶谐波。最后,我们对目前的工作进行了展望。
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引用次数: 0
Influence of crystallinity change on creep properties due to thermal history for polypropylene 热历史对聚丙烯结晶性变化对蠕变性能的影响
IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-11-05 DOI: 10.1007/s11043-025-09836-2
Takeharu Isaki, Shigenari Kanemura, Masayuki Nakada, Yasushi Miyano, Yoko Morisawa, Kiyoshi Uzawa

For crystalline polymers used as a matrix polymer at fiber-reinforced thermo-plastics, effects of crystallinity of polypropylene on creep characteristics were investigated. Measurements taken using DSC, DMA, SAXS, and WAXS elucidated crystallization behavior and crystallinity along with changes in the annealing temperature and annealing time. Although crystallinity increases with the annealing temperature and annealing time, a relation was found between the annealing temperature and time: crystallinity can be shifted by a shift factor. The time–temperature crystallinity superposition holds for crystalline polymers. Using this relation, creep time change caused by aging can be predicted. The relation between crystallinity and storage modulus (E') was described using a Takayanagi type two-phase model. We proposed a mechanical model that extends the Takayanagi type two-phase model to express the phenomenon by which the creep time increases because of increased crystallinity together with a viscous element of a model implementing the Guth–Gold model. This model can express behaviors of increasing creep time caused by increased crystallinity.

以结晶性聚合物作为纤维增强热塑性塑料的基体聚合物,研究了聚丙烯结晶度对其蠕变特性的影响。采用DSC、DMA、SAXS和WAXS进行的测量阐明了结晶行为和结晶度随退火温度和退火时间的变化。虽然结晶度随退火温度和退火时间的增加而增加,但退火温度与时间之间存在一种关系:结晶度可以通过移位因子发生移位。时间-温度结晶度叠加适用于结晶性聚合物。利用这一关系,可以预测时效引起的蠕变时间变化。采用Takayanagi型两相模型描述了结晶度与存储模量(E')之间的关系。我们提出了一个扩展Takayanagi型两相模型的力学模型,以表达由于结晶度增加而导致蠕变时间增加的现象,以及实现Guth-Gold模型的模型的粘性元素。该模型可以表达结晶度增加导致蠕变时间增加的行为。
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引用次数: 0
Prediction of yield stress and plastic viscosity of superabsorbent polymer modified cement pastes: YODEL model and Krieger-Dougherty equation 高吸水性聚合物改性水泥浆屈服应力和塑性粘度的预测:YODEL模型和Krieger-Dougherty方程
IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-11-05 DOI: 10.1007/s11043-025-09835-3
Nilam Adsul, Su-Tae Kang

This study aimed to predict the yield stress and plastic viscosity of Superabsorbent Polymer (SAP)-modified cement pastes using the Yield stress mODEL (YODEL) and the Krieger-Dougherty (K-D) equation. Predictions were made for cement pastes with SAP dosages of 0.2–0.5% (by weight of cement) and water-to-cement (w/c) ratios of 0.4–0.6, over 5–35 minutes, and were compared with experimental data. In the YODEL model, the percolation threshold ((phi _{0})) and surface-to-surface separation distance (H) were fitted. The (phi _{0}) values (0.20–0.27) decreased over time, indicating paste stiffening and reduced percolation. The values of H (1.5–3 nm) declined with higher SAP dosages and over time due to water absorption and hydration, leading to increased flocculation and stiffening. In the K-D model, intrinsic viscosity [(eta )] was adjusted; [(eta )] increased with higher SAP dosages, greater w/c ratios, and time, consistent with thickening caused by SAP water uptake and hydration. For w/c = 0.4, predictions agreed with experiments from 5–15 min, with larger deviations occurring later. For w/c = 0.5 and 0.6, predictions aligned from 5–20 min, with slight overestimations and underestimations afterward. The K-D equation generally provided close agreement with experimental viscosities, showing only minor deviations. Overall, YODEL effectively captured early-age yield stress behavior, while the K-D equation successfully predicted viscosity trends, demonstrating the combined potential of these models for describing the rheology of SAP-modified cement paste.

本研究旨在利用屈服应力模型(YODEL)和Krieger-Dougherty (K-D)方程预测高吸水性聚合物(SAP)改性水泥浆体的屈服应力和塑性粘度。对SAP用量为0.2-0.5的水泥浆体进行预测% (by weight of cement) and water-to-cement (w/c) ratios of 0.4–0.6, over 5–35 minutes, and were compared with experimental data. In the YODEL model, the percolation threshold ((phi _{0})) and surface-to-surface separation distance (H) were fitted. The (phi _{0}) values (0.20–0.27) decreased over time, indicating paste stiffening and reduced percolation. The values of H (1.5–3 nm) declined with higher SAP dosages and over time due to water absorption and hydration, leading to increased flocculation and stiffening. In the K-D model, intrinsic viscosity [(eta )] was adjusted; [(eta )] increased with higher SAP dosages, greater w/c ratios, and time, consistent with thickening caused by SAP water uptake and hydration. For w/c = 0.4, predictions agreed with experiments from 5–15 min, with larger deviations occurring later. For w/c = 0.5 and 0.6, predictions aligned from 5–20 min, with slight overestimations and underestimations afterward. The K-D equation generally provided close agreement with experimental viscosities, showing only minor deviations. Overall, YODEL effectively captured early-age yield stress behavior, while the K-D equation successfully predicted viscosity trends, demonstrating the combined potential of these models for describing the rheology of SAP-modified cement paste.
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引用次数: 0
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