Structural and Magnetic Properties of Nano Manganite La0.6Sr0.4MnO3 Obtained by Mechanochemical Synthesis Influenced by Preparation Conditions

Abstract

Single phase La0.6Sr0.4MnO3 nanoparticles with perovskite structure ( symmetry) were successfully prepared by ball milling (mechanochemical synthesis) for 1 and 10 h followed by annealing treatment at temperature 900 or 1100 °C. It was found that, the lattice parameters increase with the increase of milling time or annealing temperature. The increase of the annealing temperature results in the increase of crystallite size and the particle size. The obtained samples were found to be ferromagnetic at room temperature. The sample obtained by one hour of milling and 900 °C annealing showed high value of saturation magnetization (about 56 emu g−1) and small value of coercivity (about 31 Oe) at room temperature, while the other samples show reduced value of magnetization and higher value of coercivity. The obtained magnetic results are discussed in light of the core/shell model of nanoparticles. The effect of the presence of oxygen vacancies on the lattice parameters and magnetic properties of the obtained samples is also discussed. Highlights Single phase perovskite La0.6Sr0.4MnO3 was obtained by mechanochemical synthesis. The influence of milling time and annealing temperature on the structural and magnetic properties was studied. The lattice parameters increase with the increase of milling time or annealing temperature The crystallite size and the particle size increase with the increase of annealing temperature. All samples showed ferromagnetic behavior at room temperature. Most of the samples show reduced value of magnetization. The magnetic results were discussed by the core/shell model of nanoparticles. The formation of oxygen vacancies can affect the magnetic results.