Efficient Co-ZrO2 electrocatalyst achieves high-performance solid-state lithium-sulfur batteries

Yanyan Ma, Jianhua Yan
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Abstract

Li-S batteries are recognized as a promising secondary battery system because of their high energy density, low cost, and environmental friendliness. However, the development of Li-S batteries is mainly limited by issues such as electrode volume expansion, lithium polysulfide (LiPSs) shuttle, and slow redox reaction kinetics of sulfur. Here, a kind of solid-state Li-S battery with in situ solidified solid-state electrolytes (SSEs) is reported, which dramatically reduces the electrode/electrolyte interfacial impedance. In addition, electrospinning is used to fabricate a macroporous carbon nanofibers film (MP-CNFs) loaded with dispersed Co-ZrO2 nanodot electrocatalyst as the cathode host. The in-situ gel electrolyte can be easily infiltrated into the porous carbon nanofibers and contact the Co-ZrO2 catalyst, thus fully exerting its catalytic and conversion effects on LiPSs. The results indicate that solid-state Li-S batteries exhibit a high initial capacity of 795.5 mA h·g−1 and a capacity retention rate of ∼100% after 200 cycles at 1 C.
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高效 Co-ZrO2 电催化剂实现高性能固态锂硫电池
锂-硫电池因其能量密度高、成本低和环境友好而被认为是一种前景广阔的二次电池系统。然而,锂-S 电池的发展主要受限于电极体积膨胀、多硫化锂(LiPSs)穿梭、硫的氧化还原反应动力学缓慢等问题。本文报告了一种采用原位固化固态电解质(SSEs)的固态锂-S 电池,它能显著降低电极/电解质界面阻抗。此外,还利用电纺丝技术制备了负载分散 Co-ZrO2 纳米点电催化剂的大孔碳纳米纤维薄膜(MP-CNFs),作为阴极宿主。原位凝胶电解质很容易渗入多孔碳纳米纤维并与 Co-ZrO2 催化剂接触,从而充分发挥其对锂离子电池的催化和转化作用。结果表明,固态锂离子电池的初始容量高达 795.5 mA h-g-1,在 1 C 下循环 200 次后,容量保持率可达 100%。
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