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ZnIn2S4-based heterostructured photocatalysts for CO2 reduction: A mini review 用于还原二氧化碳的基于 ZnIn2S4 的异质结构光催化剂:微型综述
Pub Date : 2024-09-01 DOI: 10.1088/1742-6596/2838/1/012012
Yi Feng, Ruitang Guo, Zhongzhu Qiu
ZnIn2S4 (ZIS)’s superior photocatalytic CO2 reduction efficacy, coupled with its distinct layered architecture and narrow energy band profile, makes it an intriguing target for CO2 conversion studies. This article evaluates the photogenerated charge transfer mechanism and photocatalytic CO2 reduction (PCR) efficacy of varied ZIS-based heterostructure catalysts. ZIS-based heterojunctions are initially classified, ensuing discourse on advanced engineering techniques enhancing heterojunction phot catalysts’ PCR functionality like co-catalyst incorporation and morphologic manipulation. The concluding section provides an overview of the present study state and future progression in regard to ZIS-based heterostructured photocatalysts for PCR.
ZnIn2S4 (ZIS) 具有卓越的光催化二氧化碳还原效率,加上其独特的层状结构和窄能带特征,使其成为二氧化碳转化研究的一个令人感兴趣的目标。本文评估了各种基于 ZIS 的异质结构催化剂的光生电荷转移机制和光催化二氧化碳还原 (PCR) 效能。文章首先对基于 ZIS 的异质结进行了分类,然后讨论了增强异质结光催化剂 PCR 功能的先进工程技术,如助催化剂的加入和形态学处理。结论部分概述了目前用于 PCR 的基于 ZIS 的异质结构光催化剂的研究现状和未来进展。
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引用次数: 0
Optimization design of hydrogen Laval nozzle based on response surface methodology (RSM) 基于响应面法(RSM)的拉瓦尔氢气喷嘴优化设计
Pub Date : 2024-09-01 DOI: 10.1088/1742-6596/2838/1/012035
Jianyang Fang, Yusheng Ju, Liwei Mao, Shichao Pei
To conduct an in-depth study of the injection characteristics of gas fuels, the structural parameters of the nozzle are optimized. Utilizing the Response Surface Method (RSM), this study selects an inlet radius R1, outlet radius R2, throat straight radius R0, expansion half angle θ, and contraction half angle α as design parameters. Based on the validated numerical model, a response surface prediction model for outlet velocity v and mass flow rate Q is established. Using the derived expressions, the contribution and interactive effects of design variables on response variables are analyzed. The findings indicate that the outlet radius and throat radius significantly affect the outlet velocity. The outlet radius positively correlates with the outlet velocity, while the throat radius negatively correlates with it. The mass flow rate is most significantly influenced by the throat radius, increasing with its increase. With outlet velocity and mass flow rate as optimization objectives, the MOGA algorithm is applied for multi-objective optimization. The optimization results indicate that the optimized structural parameters increased the centrifugal nozzle’s atomization cone angle and mass flow rate by 1.86% and 27.4%, respectively.
为了深入研究气体燃料的喷射特性,对喷嘴的结构参数进行了优化。利用响应面法(RSM),本研究选择了入口半径 R1、出口半径 R2、喉直半径 R0、膨胀半角 θ 和收缩半角 α 作为设计参数。根据验证的数值模型,建立了出口速度 v 和质量流量 Q 的响应面预测模型。利用推导出的表达式,分析了设计变量对响应变量的贡献和交互影响。结果表明,出口半径和喉管半径对出口速度有显著影响。出口半径与出口速度呈正相关,而喉管半径与出口速度呈负相关。质量流量受喉管半径的影响最大,随着喉管半径的增大而增大。以出口速度和质量流量为优化目标,采用 MOGA 算法进行多目标优化。优化结果表明,优化后的结构参数使离心喷嘴的雾化锥角和质量流量分别提高了 1.86% 和 27.4%。
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引用次数: 0
Calcium-based nanowires for bone repair 用于骨修复的钙基纳米线
Pub Date : 2024-09-01 DOI: 10.1088/1742-6596/2838/1/012009
Yuqi Sun, Yuanbo Wang
Bone defects due to the older population, severe trauma, congenital malformations, resection of bone tumors, and infections are serious problems faced in orthopedic clinical treatment, posing great hazards to human health and life, and external interventions are generally required to promote bone healing. Considering the osteogenic promotion of calcium ions, Ca-POM nanowires were synthesized in this study to facilitate the osteogenesis process through the release of calcium ions. The cytotoxicity test showed that the material possesses good biocompatibility. Furthermore, the Alizarin Red S staining demonstrated that the material could promote osteogenesis, indicating its potential as an ideal candidate for bone repair.
老年人群、严重创伤、先天畸形、骨肿瘤切除、感染等导致的骨缺损是骨科临床治疗中面临的严重问题,对人体健康和生命造成极大危害,一般需要通过外力干预来促进骨愈合。考虑到钙离子的成骨促进作用,本研究合成了 Ca-POM 纳米线,通过释放钙离子促进成骨过程。细胞毒性测试表明,该材料具有良好的生物相容性。此外,茜素红 S 染色结果表明,该材料可促进骨生成,表明其有潜力成为骨修复的理想候选材料。
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引用次数: 0
Comparison of thermo-catalytic and photo-assisted thermo-catalytic conversion of glucose to HMF with Cr-MOFs@ZrO2 用 Cr-MOFs@ZrO2 热催化和光助热催化将葡萄糖转化为 HMF 的比较
Pub Date : 2024-09-01 DOI: 10.1088/1742-6596/2838/1/012020
Kanglu Chang, Xumei Tao
Thermo-catalytic and photo-assisted thermo-catalytic are two effective pathways for conversion of glucose. Thermo-catalytic and photo-assisted thermo-catalytic conversion of glucose was studied with Cr-MOFs@ZrO2 as catalysts in nitrogen atmosphere at 150 °C. Cr-MOFs@ZrO2 possesses simultaneously Lewis acid sites as well as Brønsted acid sites, and also has strong Brønsted acidity, so it can exhibit good thermos-catalytic performanc. When the glucose was 3 g/L, the reaction was carried out at 150 °C for 2 h with DMF as solvent, the glucose conversion was 97.9% while the HMF yield was 38%. The yield of HMF can be increased to 51.1% by adding 500w xenon lamp irradiation on the basis of thermal catalytic reaction condition. A comparison of the two reactions revealed that light-assisted thermal catalysis was more favorable for the reaction.
热催化和光助热催化是转化葡萄糖的两种有效途径。研究以 Cr-MOFs@ZrO2 为催化剂,在氮气环境下于 150 ℃ 进行了葡萄糖的热催化和光助热催化转化。Cr-MOFs@ZrO2同时具有路易斯酸位点和勃氏酸位点,并具有较强的勃氏酸性,因此具有良好的热催化性能。当葡萄糖为 3 g/L 时,以 DMF 为溶剂,在 150 °C 下反应 2 h,葡萄糖转化率为 97.9%,HMF 收率为 38%。在热催化反应条件下,加入 500 瓦氙灯照射,HMF 收率可提高到 51.1%。对两种反应进行比较后发现,光助热催化更有利于反应的进行。
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引用次数: 0
Research on the co-pyrolysis of biomass and coal 生物质和煤的联合热解研究
Pub Date : 2024-09-01 DOI: 10.1088/1742-6596/2838/1/012019
Jiaojiao Zhang, Minghang Lv, Fuli Li, Zhe Wang, Xinyu Liu
Co-pyrolysis of biomass and coal has attracted much attention as a potential energy conversion technology. In this paper, the significant effects of n-hexane insoluble substance (INS) on tar, water, and coke residue yields were analyzed in depth using statistical analysis. With INS and mixing ratio as independent variables, multivariate analysis of variance (ANOVA) was used to comprehensively investigate the effects of the interaction between the two on the yields of different pyrolysis products, revealing the significant interaction between different pyrolysis products. The genetic algorithm was used to establish an optimization model to optimize the mixing ratios of the co-pyrolysis, and the considerable differences between the experimental and theoretically calculated values of the product yields of the co-pyrolysis compounds were analyzed by statistical tests, and subgroup analyses were carried out to determine the specific differences under different mixing ratios. CNN prediction model was established, and model optimization confirmed the differences between the experimental and theoretically calculated values for different pyrolytic coupling ratio-specific ratios by data validation and subgroup analysis. The further extension and optimization of the model provide a new theoretical basis and idea for further research on the co-pyrolysis of biomass and coal, which can help to improve the energy conversion efficiency and product quality.
生物质和煤的联合热解作为一种潜在的能源转换技术备受关注。本文采用统计分析方法深入分析了正己烷不溶物(INS)对焦油、水和焦炭残渣产量的显著影响。以 INS 和混合比为自变量,采用多元方差分析(ANOVA)全面考察了两者之间的交互作用对不同热解产物产率的影响,揭示了不同热解产物之间的显著交互作用。利用遗传算法建立了优化模型,对共热解的混合比进行了优化,通过统计检验分析了共热解化合物产物产率的实验值与理论计算值之间存在的较大差异,并进行了分组分析,确定了不同混合比下的具体差异。建立了 CNN 预测模型,并通过数据验证和分组分析对模型进行了优化,确认了不同热解耦合比特定比例下实验值和理论计算值之间的差异。该模型的进一步扩展和优化为生物质与煤协同热解的进一步研究提供了新的理论依据和思路,有助于提高能源转化效率和产品质量。
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引用次数: 0
Phase sequence selection method of double-circuit transmission lines on the same tower based on a comprehensive index 基于综合指数的同塔双回路输电线路相序选择方法
Pub Date : 2024-09-01 DOI: 10.1088/1742-6596/2838/1/012039
Xiaoyan Lu, Jianqiao Hu, Zhengwei Peng, Peihua Ma, Kun Zhang, Feng Gao
The non-transposition erection of transmission lines will lead to the imbalance of electrical parameters, which will affect the protection and automatic reclosing. The best phase sequence arrangement is determined by comprehensively considering the comprehensive indexes (current imbalance, secondary current, and recovery voltage) of double transmission un-transposed lines with shared towers. PSCAD/EMTDC electromagnetic transient simulation software is applied to build a typical 750kV transmission line model for simulation analysis, and the comprehensive indexes under different phase sequence arrangements are studied. The analysis reveals that the arrangement of phase sequence exerts a significant consequence of the comprehensive index. The findings indicate that the margin and different secondary current and recovery voltage indexes, double transmission un-transposed lines with shared towers can be erected in the same direction or in different phase sequences to reduce the current imbalance.
输电线路不跨越架设会导致电气参数不平衡,影响保护和自动重合闸。综合考虑共塔双回输电线路的综合指标(电流不平衡度、二次电流、恢复电压),确定最佳相序布置。应用 PSCAD/EMTDC 电磁暂态仿真软件建立典型 750kV 输电线路模型进行仿真分析,研究不同相序布置下的综合指标。分析表明,相序排列对综合指标有显著影响。研究结果表明,裕度和不同的二次电流和恢复电压指标、共用杆塔的双回输电无跨越线路可以同向或不同相序架设,以减少电流不平衡。
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引用次数: 0
Optimization of Bacillus licheniformis’ nutrient system and oilfield trial for MEOR 地衣芽孢杆菌营养系统优化和油田 MEOR 试验
Pub Date : 2024-09-01 DOI: 10.1088/1742-6596/2838/1/012021
Dingyu Kang, Duo Sun, Zixun Yao, Zhongzhi Zhang, Zhiyong Zhang
The efficacy of microbial-enhanced oil recovery (MEOR) is contingent upon the performance of oil recovery functional bacteria. The optimization of the nutrient system for oil recovery functional bacteria can enhance their performance. In this study, the nutrient systems of the strains underwent screening and optimization procedures, utilizing single-factor combined with response surface methodology. Subsequently, field trials were conducted to assess the efficacy of MEOR. The results indicated that the carbon source in the nutrient system was sucrose, the nitrogen source was NaNO3, and the phosphorus source was a combination of KH2PO4 and Na2HPO4 (in a 1:1 ratio). The combination of the results from the single-factor experiments and the response surface experiment led to the following formulation for the strain F-T nutrient system (g/L): sucrose 10.0, NaNO3 2.0, KH2PO4 1.5, Na2HPO4 1.5, CaCl2 0.12, FeSO4 0.12, MgSO4·7H2O 0.2, Na2MoO4 0.08, yeast powder 1.0, and pH 7.2-7.5. The optimized F-T bacterium has the potential to spread oil up to a diameter of 40.50 mm. The results of the MEOR field trial indicated a 2.95 × 10 t increase in oil production, with a success rate of 83.87%. Following the implementation of MEOR, production levels were observed to decline to levels comparable to those observed prior to the intervention. This indicates that continued MEOR field applications may be necessary to further enhance crude oil recovery.
微生物强化采油(MEOR)的效果取决于采油功能菌的表现。优化采油功能菌的营养系统可以提高其性能。在本研究中,利用单因素结合响应面方法,对菌株的营养系统进行了筛选和优化。随后进行了实地试验,以评估 MEOR 的功效。结果表明,营养系统中的碳源为蔗糖,氮源为 NaNO3,磷源为 KH2PO4 和 Na2HPO4 的组合(比例为 1:1)。综合单因素实验和响应面实验的结果,菌株 F-T 营养系统的配方如下(克/升):蔗糖 10.0、NaNO3 2.0、KH2PO4 1.5、Na2HPO4 1.5、CaCl2 0.12、FeSO4 0.12、MgSO4-7H2O 0.2、Na2MoO4 0.08、酵母粉 1.0、pH 值 7.2-7.5。优化后的 F-T 细菌具有将油扩散到直径 40.50 毫米的潜力。MEOR 现场试验结果表明,产油量增加了 2.95 × 10 t,成功率为 83.87%。实施 MEOR 后,观察到产量水平下降到与干预前相当的水平。这表明,为了进一步提高原油采收率,可能有必要继续进行 MEOR 现场应用。
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引用次数: 0
Research on wind turbine blade coating erosion modeling based on Generic modeling 基于通用建模的风力涡轮机叶片涂层侵蚀建模研究
Pub Date : 2024-09-01 DOI: 10.1088/1742-6596/2838/1/012034
Yuantian Xue, Changcheng Song, Chenlai Yang
In order to improve the accuracy of the prediction of the erosion phenomenon of wind turbine blade coatings, this study incorporates the wind-sand erosion data of wind turbine blade coating flat specimens obtained through wind tunnel experiments on the basis of the widely used generalized erosion model. A prediction model that accurately reflects the erosion and wear characteristics of wind turbine blade coatings is constructed using the least squares method. All the function parts included in the model showed favorable fitting effects, and the error between the model prediction results and the measured data was limited to a tolerable range. Therefore, the model has proved to be effective in predicting the erosion rate of wind turbine blade coating materials, which provides a solid theoretical foundation for the numerical simulation of the erosion and wear of wind turbine blades in a two-phase wind-sand flow environment.
为了提高风电叶片涂层侵蚀现象预测的准确性,本研究在广泛使用的广义侵蚀模型的基础上,结合风洞实验所获得的风电叶片涂层平面试样的风沙侵蚀数据。采用最小二乘法构建了一个能准确反映风电叶片涂层侵蚀和磨损特性的预测模型。模型中的所有函数部分都显示出良好的拟合效果,模型预测结果与测量数据之间的误差被限制在可容忍的范围内。因此,该模型可有效预测风电叶片涂层材料的侵蚀速率,为风沙两相流环境下风电叶片侵蚀和磨损的数值模拟提供了坚实的理论基础。
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引用次数: 0
Enhanced heat transfer technology for solar air heaters 太阳能空气加热器的强化传热技术
Pub Date : 2024-09-01 DOI: 10.1088/1742-6596/2838/1/012022
Aixin Yang, Chunxia Zhang
Solar air heaters (SAHs) exhibited low thermal performance due to air thermal properties. To optimize the convective heat transfer between air and the absorber plate, researchers designed plenty of enhanced structures based on experimental and numerical analysis. This article reviewed the improvement methods of SAHs and emphasized the crucial role of thermodynamic models and evaluation criteria. Current research focuses on improving the convective heat transfer coefficient. In terms of enhanced structures, using flow deflectors, flow disruptors, corrugated absorber plates, and porous media improved collection efficiency. This result showed these enhanced structures could effectively further the performance of SAHs and provide new ways for sustainable energy utilization.
由于空气的热特性,太阳能空气加热器(SAH)的热性能较低。为了优化空气与吸收板之间的对流传热,研究人员根据实验和数值分析设计了大量增强型结构。本文综述了 SAH 的改进方法,并强调了热力学模型和评估标准的关键作用。目前的研究重点是提高对流传热系数。在增强结构方面,使用导流板、断流板、波纹吸收板和多孔介质提高了收集效率。结果表明,这些增强型结构可有效提高 SAH 的性能,为可持续能源利用提供新途径。
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引用次数: 0
Finite element analysis of grout-filled GFRP tube repaired corroded tubular offshore platforms 灌浆填充 GFRP 管修复腐蚀管式海上平台的有限元分析
Pub Date : 2024-09-01 DOI: 10.1088/1742-6596/2838/1/012017
Yaping Lu, Yongli Zhou, Xiaoyu Yan, Ziyang Meng, Xiaoyu Hou
Steel tubular offshore platforms are exposed to aggressive marine conditions, which leads to inevitable corrosion and degradation of the structures after a long time of service. Repairing the corroded tubular structure is not easy, especially for the members that are beneath the sea level. The current paper aims to provide an alternative approach for the repairing of corroded steel tubular platforms, by which a novel method with grout-filled GFRP tube cladding the tubular members is proposed. The conception design of the method is introduced, and the repairing process is demonstrated in detail. Then the repairing efficiency of repaired joints and platforms with different corrosion rates is investigated with finite element analysis, which proves a satisfactory reinforcement on the strength of them. The enhanced ratio is up to 117% for the T-joint under compression, and 44% for the compression brace of the K-joint, 37% for the tension brace of the K-joint, 45% for the platform. Finite element models are developed to explore the influence of the GFRP tube thickness ratio and the cube strength of grout material on its strength and repair efficiency. Then the corresponding repair structure suggestions under each corrosion rate are put forward.
海上钢管平台暴露在侵蚀性海洋条件下,经过长期使用后,结构不可避免地会发生腐蚀和退化。修复被腐蚀的管状结构并非易事,尤其是对于位于海平面以下的构件。本文旨在为修复锈蚀的钢管式平台提供一种替代方法,即采用灌浆填充 GFRP 管包覆管状构件的新方法。本文介绍了该方法的构思设计,并详细演示了修复过程。然后,通过有限元分析研究了不同腐蚀率的修复接头和平台的修复效率,结果证明对其强度的加固效果令人满意。受压 T 型接头的增强率高达 117%,K 型接头受压支撑的增强率为 44%,K 型接头受拉支撑的增强率为 37%,平台的增强率为 45%。通过建立有限元模型,探讨了 GFRP 管厚度比和灌浆材料立方体强度对其强度和修复效率的影响。然后提出了各腐蚀率下相应的修复结构建议。
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引用次数: 0
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