{"title":"Exploring Wettability of Re‐Entrant Microstructures: Effects of Geometry and Material Composition","authors":"Hoang Huy Vu, Nhat‐Khuong Nguyen, Pradip Singha, Glenn Walker, Nam‐Trung Nguyen, Navid Kashaninejad","doi":"10.1002/admi.202400626","DOIUrl":null,"url":null,"abstract":"This study systematically explores the wetting characteristics of re‐entrant microstructures, focusing on the interplay between the unique geometries and material compositions. While silicon dioxide (SiO₂) re‐entrant microstructures are previously studied, this research pioneers the fabrication of silicon carbide (SiC) re‐entrant microstructures. Through experimental approaches and theoretical analysis, the research assesses how variations in geometry and material impact wettability. Key findings reveal that SiC re‐entrant structures achieve an average contact angle of 145°, closely matching the 148° observed for SiO₂, indicating similar hydrophobic behavior. Although flat SiC surfaces exhibit higher inherent hydrophobicity than flat SiO₂ (59° vs 26° contact angle), re‐entrant geometry predominantly influences wetting behavior, overshadowing material differences. Structures with lower solid area fractions show increased hydrophobicity, with a distinct hierarchy: microlines are the least hydrophobic, followed by shark‐skin textures, rectangles, circles, and triangles. Additionally, increasing the gap size between structures enhanced hydrophobicity up to a critical point. This study paves the way for optimizing re‐entrant microstructures for specific applications, significantly enhancing the understanding of surface science and advancing material design.","PeriodicalId":115,"journal":{"name":"Advanced Materials Interfaces","volume":null,"pages":null},"PeriodicalIF":4.3000,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Materials Interfaces","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1002/admi.202400626","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
This study systematically explores the wetting characteristics of re‐entrant microstructures, focusing on the interplay between the unique geometries and material compositions. While silicon dioxide (SiO₂) re‐entrant microstructures are previously studied, this research pioneers the fabrication of silicon carbide (SiC) re‐entrant microstructures. Through experimental approaches and theoretical analysis, the research assesses how variations in geometry and material impact wettability. Key findings reveal that SiC re‐entrant structures achieve an average contact angle of 145°, closely matching the 148° observed for SiO₂, indicating similar hydrophobic behavior. Although flat SiC surfaces exhibit higher inherent hydrophobicity than flat SiO₂ (59° vs 26° contact angle), re‐entrant geometry predominantly influences wetting behavior, overshadowing material differences. Structures with lower solid area fractions show increased hydrophobicity, with a distinct hierarchy: microlines are the least hydrophobic, followed by shark‐skin textures, rectangles, circles, and triangles. Additionally, increasing the gap size between structures enhanced hydrophobicity up to a critical point. This study paves the way for optimizing re‐entrant microstructures for specific applications, significantly enhancing the understanding of surface science and advancing material design.
期刊介绍:
Advanced Materials Interfaces publishes top-level research on interface technologies and effects. Considering any interface formed between solids, liquids, and gases, the journal ensures an interdisciplinary blend of physics, chemistry, materials science, and life sciences. Advanced Materials Interfaces was launched in 2014 and received an Impact Factor of 4.834 in 2018.
The scope of Advanced Materials Interfaces is dedicated to interfaces and surfaces that play an essential role in virtually all materials and devices. Physics, chemistry, materials science and life sciences blend to encourage new, cross-pollinating ideas, which will drive forward our understanding of the processes at the interface.
Advanced Materials Interfaces covers all topics in interface-related research:
Oil / water separation,
Applications of nanostructured materials,
2D materials and heterostructures,
Surfaces and interfaces in organic electronic devices,
Catalysis and membranes,
Self-assembly and nanopatterned surfaces,
Composite and coating materials,
Biointerfaces for technical and medical applications.
Advanced Materials Interfaces provides a forum for topics on surface and interface science with a wide choice of formats: Reviews, Full Papers, and Communications, as well as Progress Reports and Research News.