Current-carrying friction behavior of CrN coatings under the influence of DC electric current discharge

IF 5.3 2区 材料科学 Q1 MATERIALS SCIENCE, COATINGS & FILMS Surface & Coatings Technology Pub Date : 2024-09-11 DOI:10.1016/j.surfcoat.2024.131356
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Abstract

CrN coatings are renowned for their low friction coefficients, high chemical inertness, excellent corrosion resistance, and substantial hardness, making them ideal for the tribological demands of bearings and gears in electric vehicles. This study investigated the current-carrying friction behavior of CrN coatings when sliding against steel balls under both non-electrified and electrified conditions. The friction coefficient (CoF), wear volume, wear type, and mechanism of the coating were reported by adjusting the direct current (DC) intensity and lubrication status. The findings indicate that while the current significantly exacerbates substrate wear during dry friction, its impact on the CrN coating is minimal. Even at a maximum DC current of 1.5 A, the wear rate of CrN coating during dry friction is only 1.9 × 10−4 mm3·(N·m)−1, representing a reduction by 79.1 % compared to the steel substrate. This effect is further pronounced when lubricated with PAO oil. The wear of CrN coating shows minimal change even as the current increased, and surface wear remains very slight. At a current of 1.5 A, the wear rate of CrN coating decreases to as low as 9.7 × 10−6 mm3·(N·m)−1, indicating a reduction by 98.7 % compared to its substrate. It is observed that under electrified conditions, the oxidation and degradation of CrN coating are accelerated, thereby resulting in the formation of a loose and low-hardness Cr2O3 oxide layer on the surface. The oxide layer is primarily attributable to the deterioration in frictional properties of the CrN coating under electrified conditions. Finally, CrN coatings exhibit minimal changes in tribological behavior under electrified conditions, thereby offering effective protection for substrates against electrical damage. Therefore, CrN coatings are ideal for applications involving electrical contacts.

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直流电流放电影响下 CrN 涂层的载流摩擦行为
CrN 涂层以摩擦系数低、化学惰性高、耐腐蚀性优异和硬度高而著称,因此非常适合电动汽车轴承和齿轮的摩擦学要求。本研究调查了 CrN 涂层在非通电和通电条件下与钢球滑动时的载流摩擦行为。通过调整直流电(DC)强度和润滑状态,报告了涂层的摩擦系数(CoF)、磨损量、磨损类型和机理。研究结果表明,虽然电流会明显加剧干摩擦过程中的基体磨损,但对 CrN 涂层的影响却微乎其微。即使在最大直流电流为 1.5 A 的情况下,干摩擦时 CrN 涂层的磨损率也仅为 1.9 × 10-4 mm3-(N-m)-1,与钢基体相比降低了 79.1%。在使用 PAO 油润滑时,这种效果更加明显。即使电流增加,CrN 涂层的磨损变化也很小,表面磨损仍然非常轻微。在电流为 1.5 A 时,CrN 涂层的磨损率降至 9.7 × 10-6 mm3-(N-m)-1,与基体相比减少了 98.7%。据观察,在通电条件下,CrN 涂层的氧化和降解速度加快,从而在表面形成了疏松且硬度较低的 Cr2O3 氧化层。在通电条件下,CrN 涂层摩擦性能下降的主要原因是氧化层。最后,在通电条件下,CrN 涂层的摩擦学性能变化极小,因此能有效保护基材免受电损伤。因此,CrN 涂层是电气接触应用的理想选择。
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来源期刊
Surface & Coatings Technology
Surface & Coatings Technology 工程技术-材料科学:膜
CiteScore
10.00
自引率
11.10%
发文量
921
审稿时长
19 days
期刊介绍: Surface and Coatings Technology is an international archival journal publishing scientific papers on significant developments in surface and interface engineering to modify and improve the surface properties of materials for protection in demanding contact conditions or aggressive environments, or for enhanced functional performance. Contributions range from original scientific articles concerned with fundamental and applied aspects of research or direct applications of metallic, inorganic, organic and composite coatings, to invited reviews of current technology in specific areas. Papers submitted to this journal are expected to be in line with the following aspects in processes, and properties/performance: A. Processes: Physical and chemical vapour deposition techniques, thermal and plasma spraying, surface modification by directed energy techniques such as ion, electron and laser beams, thermo-chemical treatment, wet chemical and electrochemical processes such as plating, sol-gel coating, anodization, plasma electrolytic oxidation, etc., but excluding painting. B. Properties/performance: friction performance, wear resistance (e.g., abrasion, erosion, fretting, etc), corrosion and oxidation resistance, thermal protection, diffusion resistance, hydrophilicity/hydrophobicity, and properties relevant to smart materials behaviour and enhanced multifunctional performance for environmental, energy and medical applications, but excluding device aspects.
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