Microstructure, mechanical and wear behavior of AlxTi(1−x)CoCrFeNi (x = 0.875, 0.75) high-entropy coatings fabricated via HVOF and post-annealing

IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Tribology International Pub Date : 2024-09-15 DOI:10.1016/j.triboint.2024.110248
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Abstract

AlxTi(1−x)CoCrFeNi (x = 0.875, 0.75) high-entropy coatings (HECs) were prepared using High-Velocity Oxygen-Fuel technology, and then underwent vacuum annealing at 500 ℃, 700 ℃, 900 ℃, and 1100 ℃, respectively. The sprayed coatings exhibited BCC phase, with the hardness increasing as the Ti content added. The wear mechanism of the HECs included abrasive, adhesion and oxidation wear. The microstructure and phase structure of the HECs annealed at 500 ℃ were basically consistent with the as-sprayed coatings. The Al0.75Ti0.25CoCrFeNi HEC nanohardness reached the peak (19.6 ± 1.1 GPa) and had the best wear resistance (1.8 ×10−5 mm3 N−1 m−1) due to the grain boundary dislocation source strengthening. With the annealing temperature increasing, the BCC to FCC phase transition occurred, the grains coarsened, the hardness decreased, and oxidation wear were intensified.

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通过 HVOF 和后退火制造的 AlxTi(1-x)CoCrFeNi (x = 0.875, 0.75) 高熵涂层的微观结构、力学和磨损行为
采用高速氧气-燃料技术制备了 AlxTi(1-x)CoCrFeNi (x = 0.875, 0.75) 高熵涂层(HECs),然后分别在 500 ℃、700 ℃、900 ℃ 和 1100 ℃ 下进行真空退火。喷涂涂层呈现 BCC 相,硬度随着钛含量的增加而增加。HECs 的磨损机理包括磨料磨损、附着磨损和氧化磨损。在 500 ℃ 下退火的 HEC 的微观结构和相结构与喷涂涂层基本一致。由于晶界位错源强化,Al0.75Ti0.25CoCrFeNi HEC 纳米硬度达到峰值(19.6 ± 1.1 GPa),耐磨性最好(1.8 ×10-5 mm3 N-1 m-1)。随着退火温度的升高,发生了 BCC 到 FCC 的相变,晶粒变粗,硬度降低,氧化磨损加剧。
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来源期刊
Tribology International
Tribology International 工程技术-工程:机械
CiteScore
10.10
自引率
16.10%
发文量
627
审稿时长
35 days
期刊介绍: Tribology is the science of rubbing surfaces and contributes to every facet of our everyday life, from live cell friction to engine lubrication and seismology. As such tribology is truly multidisciplinary and this extraordinary breadth of scientific interest is reflected in the scope of Tribology International. Tribology International seeks to publish original research papers of the highest scientific quality to provide an archival resource for scientists from all backgrounds. Written contributions are invited reporting experimental and modelling studies both in established areas of tribology and emerging fields. Scientific topics include the physics or chemistry of tribo-surfaces, bio-tribology, surface engineering and materials, contact mechanics, nano-tribology, lubricants and hydrodynamic lubrication.
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