{"title":"Microstructure and tensile properties of in-situ TiAl nanoparticles reinforced AZ31 composites","authors":"","doi":"10.1016/j.matchar.2024.114381","DOIUrl":null,"url":null,"abstract":"<div><p>The good interfacial bonding between reinforcements and magnesium (Mg) matrix is the essential requirement for the development of magnesium matrix composites (MMCs) with high performance. Herein, this work tries to improve the interfacial bonding of MMCs. Here, the pre-dispersed Ti nanoparticles were introduced in AZ31 composites to form in-situ TiAl nanoparticles, and the AZ31 composites were synthesized by semisolid stirring assisted ultrasonic vibration method. Microstructural analysis reveals that the TiAl nanoparticles are in-situ formed by the Al atoms in composites diffusing into Ti nanoparticles, and the composites obtain a strong interfacial bonding between the TiAl nanoparticles and matrix owing to the formation of TiAl/Mg semi-coherent interface. The composites achieve simultaneous improvement of strength and plasticity. The composite with 0.2 wt% Ti nanoparticles addition possesses the best comprehensive tensile properties. The corresponding ultimate tensile strength and elongation reach 315 MPa and 21.3 %, respectively. The enhanced strength is owing to dislocation strengthening, grain refinement strengthening, and Orowan strengthening. The good plasticity is the result of the activation of non-basal dislocations, refined grains, weakened texture, and good interfacial bonding.</p></div>","PeriodicalId":18727,"journal":{"name":"Materials Characterization","volume":null,"pages":null},"PeriodicalIF":4.8000,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Characterization","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1044580324007629","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CHARACTERIZATION & TESTING","Score":null,"Total":0}
引用次数: 0
Abstract
The good interfacial bonding between reinforcements and magnesium (Mg) matrix is the essential requirement for the development of magnesium matrix composites (MMCs) with high performance. Herein, this work tries to improve the interfacial bonding of MMCs. Here, the pre-dispersed Ti nanoparticles were introduced in AZ31 composites to form in-situ TiAl nanoparticles, and the AZ31 composites were synthesized by semisolid stirring assisted ultrasonic vibration method. Microstructural analysis reveals that the TiAl nanoparticles are in-situ formed by the Al atoms in composites diffusing into Ti nanoparticles, and the composites obtain a strong interfacial bonding between the TiAl nanoparticles and matrix owing to the formation of TiAl/Mg semi-coherent interface. The composites achieve simultaneous improvement of strength and plasticity. The composite with 0.2 wt% Ti nanoparticles addition possesses the best comprehensive tensile properties. The corresponding ultimate tensile strength and elongation reach 315 MPa and 21.3 %, respectively. The enhanced strength is owing to dislocation strengthening, grain refinement strengthening, and Orowan strengthening. The good plasticity is the result of the activation of non-basal dislocations, refined grains, weakened texture, and good interfacial bonding.
增强材料与镁(Mg)基体之间良好的界面结合是开发高性能镁基复合材料(MMC)的基本要求。本研究试图改善镁基复合材料的界面结合。本文在 AZ31 复合材料中引入了预分散的 Ti 纳米粒子,在原位形成 TiAl 纳米粒子,并采用半固态搅拌辅助超声振动法合成了 AZ31 复合材料。微观结构分析表明,TiAl 纳米粒子是由复合材料中的 Al 原子向 Ti 纳米粒子中扩散而原位形成的,由于 TiAl/Mg 半相干界面的形成,TiAl 纳米粒子与基体之间获得了很强的界面结合力。复合材料同时提高了强度和塑性。添加 0.2 wt% Ti 纳米颗粒的复合材料具有最佳的综合拉伸性能。相应的极限拉伸强度和伸长率分别达到 315 兆帕和 21.3%。强度的提高得益于位错强化、晶粒细化强化和奥罗旺强化。良好的塑性则是非基底位错活化、晶粒细化、质地弱化和良好的界面结合的结果。
期刊介绍:
Materials Characterization features original articles and state-of-the-art reviews on theoretical and practical aspects of the structure and behaviour of materials.
The Journal focuses on all characterization techniques, including all forms of microscopy (light, electron, acoustic, etc.,) and analysis (especially microanalysis and surface analytical techniques). Developments in both this wide range of techniques and their application to the quantification of the microstructure of materials are essential facets of the Journal.
The Journal provides the Materials Scientist/Engineer with up-to-date information on many types of materials with an underlying theme of explaining the behavior of materials using novel approaches. Materials covered by the journal include:
Metals & Alloys
Ceramics
Nanomaterials
Biomedical materials
Optical materials
Composites
Natural Materials.