Growth, magnetic, and electronic properties of Ni-Zn ferrites thin films

IF 1.8 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Materials Research Express Pub Date : 2024-09-17 DOI:10.1088/2053-1591/ad78ae
L G Guzman, L C Sánchez, J Gil Monsalve, C Ostos and O Arnache
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Abstract

Thin films of Ni-Zn ferrite grown on MgO(111) single crystal substrate were prepared using radiofrequency magnetron sputtering, with a target of nominal composition Ni0.5Zn0.5Fe2O4. Subsequently, x-ray diffraction (XRD) was performed, which revealed characteristic reflections of a Ni-Zn ferrite structure, confirming the unique formation of the ferrite. X-ray photoelectron spectroscopy (XPS) revealed the presence of metal ions in their appropriate valence states within the crystalline structure of the Ni-Zn ferrite. The variation in binding energy observed in the thin film is attributed to changes in the environment of Fe3+ and Zn2+ or Ni2+ ions, resulting from the non-equilibrium distribution of cations in tetrahedral and octahedral sites. The saturation magnetization and the coercivity field were and 513 ± 32 Oe, respectively. In addition, ferromagnetic resonance studies were made using broad-band FMR spectroscopy based on a coplanar waveguide (CPW) spectrometer.
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镍锌铁氧体薄膜的生长、磁性和电子特性
使用射频磁控溅射法制备了生长在氧化镁(111)单晶衬底上的镍锌铁氧体薄膜,靶材的标称成分为 Ni0.5Zn0.5Fe2O4。随后进行了 X 射线衍射 (XRD),发现了镍锌铁氧体结构的特征反射,证实了铁氧体的独特形成。X 射线光电子能谱(XPS)显示,在镍锌铁氧体的晶体结构中存在适当价态的金属离子。在薄膜中观察到的结合能变化归因于 Fe3+ 和 Zn2+ 或 Ni2+ 离子环境的变化,这是阳离子在四面体和八面体位点的非平衡分布造成的。饱和磁化和矫顽力场分别为和 513 ± 32 Oe。此外,还利用基于共面波导(CPW)光谱仪的宽带 FMR 光谱进行了铁磁共振研究。
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来源期刊
Materials Research Express
Materials Research Express MATERIALS SCIENCE, MULTIDISCIPLINARY-
CiteScore
4.50
自引率
4.30%
发文量
640
审稿时长
12 weeks
期刊介绍: A broad, rapid peer-review journal publishing new experimental and theoretical research on the design, fabrication, properties and applications of all classes of materials.
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