Repairment of carbon steel oxide scale using Ce³⁺ and Ni²⁺ doped sol-gel technique

Abstract

Corrosion of carbon steel rebars in concrete structures significantly compromises their safety, reliability, and environmental performance. This work focuses on enhancing rebar corrosion resistance by repairing the defects of oxide scale. Here, sol-gel was employed as a carrier, by which Ce3+ and Ni2+ were transferred to the oxide scale defects based on the isoelectric point theory, and deposited at these defects with the pH variation as temperature. The repaired oxide scale showed enhanced uniform elemental distribution and improved electrochemical properties, maintaining integrity even under prolonged exposure to Cl−-rich environments. Notably, the impedance modulus at 0.01 Hz (|Z | 0.01Hz) of treated samples was six times higher than untreated ones, indicating superior performance against high electric fields. This strategy shows great potential for enhancing the durability of concrete structures.