Flame propagation characteristics of non-uniform premixed hydrogen-air mixtures explosion in a pipeline

IF 8.1 2区 工程技术 Q1 CHEMISTRY, PHYSICAL International Journal of Hydrogen Energy Pub Date : 2024-09-21 DOI:10.1016/j.ijhydene.2024.09.235
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Abstract

Hydrogen, as a clean and promising energy carrier, is considered a viable alternative fuel for the future. However, accidental hydrogen leakages and explosions pose considerable safety concerns in hydrogen energy applications and process industries. This study investigated the flame propagation characteristics of non-uniform premixed hydrogen-air mixtures in a rectangular closed duct with a length-to-diameter ratio of 5.78, taking into account varying equivalence ratios and diffusion times. First, numerical simulations using FLUENT were conducted to model the hydrogen diffusion process in a confined space, determining the hydrogen concentration evolution post-leakage. After approximately 200 s of diffusion, the premixed hydrogen-air mixtures remained in a state of homogeneous mixing, with the hydrogen concentration stabilizing at approximately 1.25 × 10−2 kg/m³. Subsequently, experimental observations were performed using a visual pipeline system, high-speed photography, and flame structure analysis. These experiments examined inhomogeneous hydrogen-air mixtures under seven different equivalence ratios and five different diffusion time conditions. The effects of equivalence ratios and diffusion times on flame propagation characteristics were analyzed. The results revealed that equivalence ratio significantly influenced the flame structure, with higher equivalence ratios producing more pronounced flame surface wrinkles. However, the typical evolution of the tulip flame remained consistent. At a constant equivalence ratio, flame propagation velocity exhibited an initial increase followed by a decrease over time. These findings demonstrate that turbulence intensity accelerated the flame propagation in non-uniform premixed hydrogen-air mixtures. This study underscores the importance of further research on hydrogen safety fundamentals and technologies to develop comprehensive safety standards.

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非均匀预混氢气-空气混合物在管道中爆炸的火焰传播特性
氢作为一种清洁且前景广阔的能源载体,被认为是未来可行的替代燃料。然而,氢气的意外泄漏和爆炸给氢能应用和加工工业带来了相当大的安全隐患。本研究考察了非均匀预混合氢气-空气混合物在长径比为 5.78 的矩形封闭管道中的火焰传播特性,并考虑了不同的等效比和扩散时间。首先,使用 FLUENT 对密闭空间中的氢气扩散过程进行了数值模拟,确定了泄漏后氢气浓度的变化情况。经过约 200 秒的扩散后,预混合氢气-空气混合物仍处于均匀混合状态,氢气浓度稳定在约 1.25 × 10-2 kg/m³。随后,利用可视管道系统、高速摄影和火焰结构分析进行了实验观察。这些实验研究了七种不同当量比和五种不同扩散时间条件下的不均匀氢气-空气混合物。分析了等效比和扩散时间对火焰传播特性的影响。结果表明,等效比对火焰结构有显著影响,等效比越高,火焰表面皱纹越明显。然而,郁金香火焰的典型演变过程保持一致。在等效比不变的情况下,火焰的传播速度呈现出先上升后下降的趋势。这些发现表明,湍流强度加速了非均匀预混合氢气-空气混合物中火焰的传播。这项研究强调了进一步研究氢气安全基础和技术以制定全面安全标准的重要性。
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来源期刊
International Journal of Hydrogen Energy
International Journal of Hydrogen Energy 工程技术-环境科学
CiteScore
13.50
自引率
25.00%
发文量
3502
审稿时长
60 days
期刊介绍: The objective of the International Journal of Hydrogen Energy is to facilitate the exchange of new ideas, technological advancements, and research findings in the field of Hydrogen Energy among scientists and engineers worldwide. This journal showcases original research, both analytical and experimental, covering various aspects of Hydrogen Energy. These include production, storage, transmission, utilization, enabling technologies, environmental impact, economic considerations, and global perspectives on hydrogen and its carriers such as NH3, CH4, alcohols, etc. The utilization aspect encompasses various methods such as thermochemical (combustion), photochemical, electrochemical (fuel cells), and nuclear conversion of hydrogen, hydrogen isotopes, and hydrogen carriers into thermal, mechanical, and electrical energies. The applications of these energies can be found in transportation (including aerospace), industrial, commercial, and residential sectors.
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