Lai-Ma Luo , Xi-Peng Ding , Wang-Zhi Xu , Cai-Yan Wang , Yong-Qiang Qin , Yu-Cheng Wu
{"title":"Strengthening mechanisms and research progress in the W/Cu interfaces","authors":"Lai-Ma Luo , Xi-Peng Ding , Wang-Zhi Xu , Cai-Yan Wang , Yong-Qiang Qin , Yu-Cheng Wu","doi":"10.1016/j.ijrmhm.2024.106900","DOIUrl":null,"url":null,"abstract":"<div><div>Tungsten‑copper (W<img>Cu) composites integrate the high melting point, strength, and superior wear and arc resistance of tungsten with the exceptional electrical and thermal conductivity and good plasticity of copper. This combination makes them ideal for applications requiring high thermal conductivity and resistance to high temperatures. However, producing high-quality composites is challenging due to the significant differences in crystal structure and physical properties between tungsten and copper. Under high temperature load conditions, the W<img>Cu interface is subjected to substantial thermal stresses, which can lead to crack formation and eventual material failure. This review systematically analyzes methods to enhance the bonding strength of the W/Cu interface, suppress crack initiation and propagation, and mitigate interface thermal stresses. The focus is on physical bonding, chemical bonding, and the design and preparation of W<img>Cu functionally graded materials (FGMs). The mechanisms for strengthening the W/Cu interface are elucidated. Additionally, this review addresses the effects of grain refinement and work hardening at the interface on the microstructure and overall properties of W<img>Cu composites. Finally, the review summarizes the prospects for W/Cu interface research and highlights the challenges for future investigations.</div></div>","PeriodicalId":14216,"journal":{"name":"International Journal of Refractory Metals & Hard Materials","volume":"125 ","pages":"Article 106900"},"PeriodicalIF":4.2000,"publicationDate":"2024-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Refractory Metals & Hard Materials","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0263436824003482","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Tungsten‑copper (WCu) composites integrate the high melting point, strength, and superior wear and arc resistance of tungsten with the exceptional electrical and thermal conductivity and good plasticity of copper. This combination makes them ideal for applications requiring high thermal conductivity and resistance to high temperatures. However, producing high-quality composites is challenging due to the significant differences in crystal structure and physical properties between tungsten and copper. Under high temperature load conditions, the WCu interface is subjected to substantial thermal stresses, which can lead to crack formation and eventual material failure. This review systematically analyzes methods to enhance the bonding strength of the W/Cu interface, suppress crack initiation and propagation, and mitigate interface thermal stresses. The focus is on physical bonding, chemical bonding, and the design and preparation of WCu functionally graded materials (FGMs). The mechanisms for strengthening the W/Cu interface are elucidated. Additionally, this review addresses the effects of grain refinement and work hardening at the interface on the microstructure and overall properties of WCu composites. Finally, the review summarizes the prospects for W/Cu interface research and highlights the challenges for future investigations.
期刊介绍:
The International Journal of Refractory Metals and Hard Materials (IJRMHM) publishes original research articles concerned with all aspects of refractory metals and hard materials. Refractory metals are defined as metals with melting points higher than 1800 °C. These are tungsten, molybdenum, chromium, tantalum, niobium, hafnium, and rhenium, as well as many compounds and alloys based thereupon. Hard materials that are included in the scope of this journal are defined as materials with hardness values higher than 1000 kg/mm2, primarily intended for applications as manufacturing tools or wear resistant components in mechanical systems. Thus they encompass carbides, nitrides and borides of metals, and related compounds. A special focus of this journal is put on the family of hardmetals, which is also known as cemented tungsten carbide, and cermets which are based on titanium carbide and carbonitrides with or without a metal binder. Ceramics and superhard materials including diamond and cubic boron nitride may also be accepted provided the subject material is presented as hard materials as defined above.