Correlating the microstructure of titanium hydride with its hydrogenation conditions via thermodynamics and kinetics

Abstract

Titanium hydride is widely considered as an important hydrogen storage material due to its high capacity, stability and low cost. The microstructure of titanium hydride, which is usually induced by the hydrogenation of titanium, strongly influences its storage performance. However, the relationship between the hydrogenation conditions and the derived microstructure of titanium hydride is still unclear, limiting the development of its structure design strategy. In this work, the microstructure of titanium hydride is correlated with its hydrogenation conditions through the thermodynamics and kinetics. By evaluating the effects of the hydrogenation temperature, pressure and cooling rate, three classes of the hydrogenation processes were clarified: kinetic-limited, continuous and stepwise. Besides, according to the SEM and FIB-STEM results, these different processes are confirmed to greatly vary the bulk microstructure. It is concluded that a fast and continuous transition induces a broken bulk morphology, while a stepwise process leads to a larger bulk grain size. In summary, this study presents a framework for designing titanium hydride structures by modifying phase transition processes through careful adjustment of hydrogenation parameters, namely, a condition-process-structure relationship. This relationship offers crucial guidance in managing the grain refinement or coarsening of hydrides within hydrogen storage components and metallurgical applications.