{"title":"Electro-Fenton enhanced MBR for fouling alleviation based on MIL-88B-Fe derived carbon membrane with in-situ generated OH","authors":"","doi":"10.1016/j.seppur.2024.129853","DOIUrl":null,"url":null,"abstract":"<div><div>Porous carbon membrane (PCM) derived from MIL-88B-Fe with the ability of in-situ generation of hydroxyl radical was introduced to electro-enhanced aerobic membrane bioreactor (EMBR) for membrane fouling mitigation and wastewater quality improvement. The resultant PCM obtained with the calcination temperature of 1000 °C owned significant enhancement on hydrophilic and conductive properties, which helped PCM under −1.2 V could completely remove 10 mg/L bovine serum albumin with 2.5 % membrane flux loss rate. During the 76-day operation of EMBR, the extracellular polymeric substances could be suppressed for depositing on the −1.2 V enhanced PCM due to the combined effect of electrostatic barrier and <sup><img></sup>OH oxidation. The pollutant intensity of total cells, polysaccharides and proteins were all reduced on PCM with −1.2 V. After operation, 36.0 % of cake layer pores was blocked in EMBR by total cells, polysaccharides and proteins. However, it was accounted for 69.8 % of the control group. Above results explained why the EMBR owned an always lower transmembrane pressure. Meanwhile, the pollutants removal rates of COD and NH<sub>4</sub><sup>+</sup>-N were as high as 95 % and 98 % with electro-enhanced filtration, respectively, which is attributed to the collaborated effect from electrochemical effect and significantly increased microbial species related to organic pollutants removal, such as <em>Azohydromonas</em>, <em>Thermomonas</em>.</div></div>","PeriodicalId":427,"journal":{"name":"Separation and Purification Technology","volume":null,"pages":null},"PeriodicalIF":8.1000,"publicationDate":"2024-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Separation and Purification Technology","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1383586624035925","RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Porous carbon membrane (PCM) derived from MIL-88B-Fe with the ability of in-situ generation of hydroxyl radical was introduced to electro-enhanced aerobic membrane bioreactor (EMBR) for membrane fouling mitigation and wastewater quality improvement. The resultant PCM obtained with the calcination temperature of 1000 °C owned significant enhancement on hydrophilic and conductive properties, which helped PCM under −1.2 V could completely remove 10 mg/L bovine serum albumin with 2.5 % membrane flux loss rate. During the 76-day operation of EMBR, the extracellular polymeric substances could be suppressed for depositing on the −1.2 V enhanced PCM due to the combined effect of electrostatic barrier and OH oxidation. The pollutant intensity of total cells, polysaccharides and proteins were all reduced on PCM with −1.2 V. After operation, 36.0 % of cake layer pores was blocked in EMBR by total cells, polysaccharides and proteins. However, it was accounted for 69.8 % of the control group. Above results explained why the EMBR owned an always lower transmembrane pressure. Meanwhile, the pollutants removal rates of COD and NH4+-N were as high as 95 % and 98 % with electro-enhanced filtration, respectively, which is attributed to the collaborated effect from electrochemical effect and significantly increased microbial species related to organic pollutants removal, such as Azohydromonas, Thermomonas.
期刊介绍:
Separation and Purification Technology is a premier journal committed to sharing innovative methods for separation and purification in chemical and environmental engineering, encompassing both homogeneous solutions and heterogeneous mixtures. Our scope includes the separation and/or purification of liquids, vapors, and gases, as well as carbon capture and separation techniques. However, it's important to note that methods solely intended for analytical purposes are not within the scope of the journal. Additionally, disciplines such as soil science, polymer science, and metallurgy fall outside the purview of Separation and Purification Technology. Join us in advancing the field of separation and purification methods for sustainable solutions in chemical and environmental engineering.