{"title":"Chemical Pressure-Driven Band Convergence and Discordant Atoms Intensify Phonon Scattering Leading to High Thermoelectric Performance in SnTe.","authors":"Hongwei Ming, Zhong-Zhen Luo, Zixuan Chen, Hong-Hua Cui, Wenwen Zheng, Zhigang Zou, Mercouri G Kanatzidis","doi":"10.1021/jacs.4c10286","DOIUrl":null,"url":null,"abstract":"<p><p>SnTe is an intriguing alternative to PbTe for midtemperature thermoelectric applications. Despite steady progress, its performance is lagging, in part because of the large energy difference(Δ<i>E</i><sub>L-Σ</sub>) between the light (L-band) and heavy (Σ-band) valence bands and higher lattice thermal conductivity (κ<sub>L</sub>). Previous studies have shown that applying pressure can enhance the Seebeck coefficient (<i>S</i>) and power factor (<i>PF</i>) of SnTe. Inspired by this study, we showcase how the high-pressure effect can be emulated under ambient pressure by substituting Sn with atoms possessing smaller atomic radii. Specifically, Sb- and Ge-doping combined with CdTe- or CdS-alloying induce lattice shrinkage, also referred to as \"chemical pressure\", raising the energy of the Σ-band. Additionally, these substituted atoms lower the contribution of Sn 5s-Te 5p antibonding states to the L-band, thereby reducing its energy and dispersion. These combined effects decrease Δ<i>E</i><sub>L-Σ</sub> from 0.36 to 0.09 eV, leading to the enhanced <i>S</i> and average <i>PF</i><sub>avg</sub>. Notably, the <i>PF</i><sub>avg</sub>, ranging from 323 to 873 K, increases from 8.1 μW cm<sup>-1</sup> K<sup>-2</sup> for pristine SnTe to 21.6 μW cm<sup>-1</sup> K<sup>-2</sup> for Sn<sub>0.79</sub>Ge<sub>0.15</sub>Sb<sub>0.06</sub>Te-5% CdTe. Furthermore, the intensified phonon scattering resulting from discordant nature of Ge and Cd atoms, creating point defects soften phonon modes, and the presence of Ge-rich nanoprecipitates lead to a substantial 62% reduction in κ<sub>L</sub> at 873 K. This strong valence band convergence and enhanced phonon scattering collectively contribute to a high peak <i>ZT</i> of 1.5 (873 K) and high average <i>ZT</i><sub>avg</sub> = 0.81 over the temperature range of 323-873 K.</p>","PeriodicalId":49,"journal":{"name":"Journal of the American Chemical Society","volume":null,"pages":null},"PeriodicalIF":14.4000,"publicationDate":"2024-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the American Chemical Society","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1021/jacs.4c10286","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
SnTe is an intriguing alternative to PbTe for midtemperature thermoelectric applications. Despite steady progress, its performance is lagging, in part because of the large energy difference(ΔEL-Σ) between the light (L-band) and heavy (Σ-band) valence bands and higher lattice thermal conductivity (κL). Previous studies have shown that applying pressure can enhance the Seebeck coefficient (S) and power factor (PF) of SnTe. Inspired by this study, we showcase how the high-pressure effect can be emulated under ambient pressure by substituting Sn with atoms possessing smaller atomic radii. Specifically, Sb- and Ge-doping combined with CdTe- or CdS-alloying induce lattice shrinkage, also referred to as "chemical pressure", raising the energy of the Σ-band. Additionally, these substituted atoms lower the contribution of Sn 5s-Te 5p antibonding states to the L-band, thereby reducing its energy and dispersion. These combined effects decrease ΔEL-Σ from 0.36 to 0.09 eV, leading to the enhanced S and average PFavg. Notably, the PFavg, ranging from 323 to 873 K, increases from 8.1 μW cm-1 K-2 for pristine SnTe to 21.6 μW cm-1 K-2 for Sn0.79Ge0.15Sb0.06Te-5% CdTe. Furthermore, the intensified phonon scattering resulting from discordant nature of Ge and Cd atoms, creating point defects soften phonon modes, and the presence of Ge-rich nanoprecipitates lead to a substantial 62% reduction in κL at 873 K. This strong valence band convergence and enhanced phonon scattering collectively contribute to a high peak ZT of 1.5 (873 K) and high average ZTavg = 0.81 over the temperature range of 323-873 K.
期刊介绍:
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