{"title":"Ultra-Durable Solar-Driven Seawater Electrolysis for Sustainable Hydrogen Production","authors":"Zhaolong Wang, Ciwei Wu, Xiaolong Wang, Mingzhu Xie, Yinfeng Li, Ziheng Zhan, Yong Shuai","doi":"10.1002/adfm.202416014","DOIUrl":null,"url":null,"abstract":"Ions in seawater hinder direct sewage electrolysis due to the extreme corrosion of Cl<sup>−</sup> to the anode and reaction of Mg<sup>2+</sup> and Ca<sup>2+</sup> on the cathode producing solid substances, which reduce the electrolytic efficiency. However, traditional desalination consuming fossil fuel with massive CO<sub>2</sub> emissions threatens human survival. Therefore, zero-carbon emission, ultra-durable, large-scale production of freshwater from seawater for water electrolysis is urgently needed. Herein, a multifunctional system for seawater is demonstrated electrolysis based on ultra-durable solar desalination outdoors. The solar evaporators reach an evaporation flux of 1.88 kg m<sup>−2</sup> h<sup>−1</sup> with a photothermal conversion efficiency of solar energy as high as 91.3% with excellent ultra-durable salt resistance even for saturated saltwater due to the Marangoni effects. Moreover, the condensation of pure water from solar desalination based on the evaporation system reaches 0.54 L m<sup>−2</sup> h<sup>−1</sup> outdoors, which is suitable for a 20 cm × 20 cm engineered electrode equipped with a Janus membrane powered by a solar panel to produce H<sub>2</sub> outdoors. The ultrafast unidirectional transport of H<sub>2</sub> bubbles enabled by Janus membranes can greatly improve the H<sub>2</sub> production efficiency at a rate approaching 85 mL h<sup>−1</sup> for continuous 24 h outdoors.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":null,"pages":null},"PeriodicalIF":18.5000,"publicationDate":"2024-10-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Functional Materials","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1002/adfm.202416014","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Ions in seawater hinder direct sewage electrolysis due to the extreme corrosion of Cl− to the anode and reaction of Mg2+ and Ca2+ on the cathode producing solid substances, which reduce the electrolytic efficiency. However, traditional desalination consuming fossil fuel with massive CO2 emissions threatens human survival. Therefore, zero-carbon emission, ultra-durable, large-scale production of freshwater from seawater for water electrolysis is urgently needed. Herein, a multifunctional system for seawater is demonstrated electrolysis based on ultra-durable solar desalination outdoors. The solar evaporators reach an evaporation flux of 1.88 kg m−2 h−1 with a photothermal conversion efficiency of solar energy as high as 91.3% with excellent ultra-durable salt resistance even for saturated saltwater due to the Marangoni effects. Moreover, the condensation of pure water from solar desalination based on the evaporation system reaches 0.54 L m−2 h−1 outdoors, which is suitable for a 20 cm × 20 cm engineered electrode equipped with a Janus membrane powered by a solar panel to produce H2 outdoors. The ultrafast unidirectional transport of H2 bubbles enabled by Janus membranes can greatly improve the H2 production efficiency at a rate approaching 85 mL h−1 for continuous 24 h outdoors.
期刊介绍:
Firmly established as a top-tier materials science journal, Advanced Functional Materials reports breakthrough research in all aspects of materials science, including nanotechnology, chemistry, physics, and biology every week.
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