Metal-organic framework-derived hierarchical flower-like DyCo-layered double hydroxide amalgamated nitrogen-doped graphene for diphenylamine detection in fruit samples: Theoretical density functional theory interpretation

Abstract

Diphenylamine (DPA) is an environmental pollutant that can be potentially toxic. As a result, it is crucial to use basic and affordable analytical techniques to detect DPA. Electrochemical detection of DPA is a cost-effective and simple method. Modifying the electrodes with nanomaterials can enhance the electrochemical characteristics and sensitivity of the sensor. Herein, metal-organic framework (MOF) derived dysprosium cobalt-layered double hydroxide integrated nitrogen-doped graphene (DyCo-LDH/NG) is reported for the fabrication of the DPA sensing platform. The electrochemical oxidation of DPA is enhanced by the exceptional electrocatalytic activity and electron transfer properties of the DyCo-LDH/NG nanocomposite. Interestingly, the glassy carbon electrode (GCE) modified with DyCo-LDH/NG nanocomposite demonstrates a large linear detection range (0.05–470 μM) and a low limit of detection (0.012 µM). The density functional theory (DFT) study is employed to examine the energy levels and electron transfer sites of DPA during the electro-oxidation process. Furthermore, the practical efficiency test of the developed DPA sensor demonstrates a substantial recovery in fruit samples.