{"title":"Optimizing Interface Chemistry with Novel Covalent Molecule for Highly Sustainable and Kinetics-Enhanced Sodium Metal Batteries","authors":"Xiaolong Cheng, Dongjun Li, Yu Yao, Fanfan Liu, Biao Ma, Pengcheng Shi, Yu Shao, Fangzhi Huang, Yingjie Sun, Yu Jiang, Shikuo Li","doi":"10.1016/j.ensm.2024.103898","DOIUrl":null,"url":null,"abstract":"Metallic sodium has attracted increasing attention as an ideal anode material for next-generation high energy density and low-cost secondary batteries. However, it is highly desired yet remains challenging to improve their cycling stability and safety due to unstable solid electrolyte interphase and dendrite growth. Herein, a hybrid interface layer composed of Na<sub>2</sub>Se and Na<sub>3</sub>P is constructed on the surface of Na (Na@NPS) via in situ spontaneous reaction. The hybrid interface layer with merits of high sodiophilicity and high Na-ion conductivity can effectively induce homogeneous Na-ion flux distribution, accelerate the reaction kinetics and suppress decomposition of electrolyte components. Benefitting from the above advantages, the Na@NPS symmetric cell delivers a long cycle life (1000 h at 1 mA cm<sup>–2</sup> and 1 mAh cm<sup>–2</sup>). Furthermore, the full cell coupling with Na<sub>3</sub>V<sub>2</sub>(PO<sub>4</sub>)<sub>3</sub>-based cathode provides an exceptionally long lifespan (1500 cycles) at 20 C with a capacity retention of 98.2% and high energy density (226 Wh kg<sup>–1</sup>). Therefore, the enhanced electrochemical performance illustrates the feasibility of the covalent molecule derived hybrid multifunctional interfaces in solving the irregular deposition of Na-ion and expediting reaction kinetics in Na metal batteries.","PeriodicalId":306,"journal":{"name":"Energy Storage Materials","volume":null,"pages":null},"PeriodicalIF":18.9000,"publicationDate":"2024-11-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Energy Storage Materials","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1016/j.ensm.2024.103898","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Metallic sodium has attracted increasing attention as an ideal anode material for next-generation high energy density and low-cost secondary batteries. However, it is highly desired yet remains challenging to improve their cycling stability and safety due to unstable solid electrolyte interphase and dendrite growth. Herein, a hybrid interface layer composed of Na2Se and Na3P is constructed on the surface of Na (Na@NPS) via in situ spontaneous reaction. The hybrid interface layer with merits of high sodiophilicity and high Na-ion conductivity can effectively induce homogeneous Na-ion flux distribution, accelerate the reaction kinetics and suppress decomposition of electrolyte components. Benefitting from the above advantages, the Na@NPS symmetric cell delivers a long cycle life (1000 h at 1 mA cm–2 and 1 mAh cm–2). Furthermore, the full cell coupling with Na3V2(PO4)3-based cathode provides an exceptionally long lifespan (1500 cycles) at 20 C with a capacity retention of 98.2% and high energy density (226 Wh kg–1). Therefore, the enhanced electrochemical performance illustrates the feasibility of the covalent molecule derived hybrid multifunctional interfaces in solving the irregular deposition of Na-ion and expediting reaction kinetics in Na metal batteries.
期刊介绍:
Energy Storage Materials is a global interdisciplinary journal dedicated to sharing scientific and technological advancements in materials and devices for advanced energy storage and related energy conversion, such as in metal-O2 batteries. The journal features comprehensive research articles, including full papers and short communications, as well as authoritative feature articles and reviews by leading experts in the field.
Energy Storage Materials covers a wide range of topics, including the synthesis, fabrication, structure, properties, performance, and technological applications of energy storage materials. Additionally, the journal explores strategies, policies, and developments in the field of energy storage materials and devices for sustainable energy.
Published papers are selected based on their scientific and technological significance, their ability to provide valuable new knowledge, and their relevance to the international research community.