Hydrothermal liquefaction for producing liquid fuels and chemicals from biomass-derived platform compounds: a review

IF 15 2区 环境科学与生态学 Q1 CHEMISTRY, MULTIDISCIPLINARY Environmental Chemistry Letters Pub Date : 2024-11-10 DOI:10.1007/s10311-024-01791-7
Bingbing Qiu, Xuedong Tao, Yanfang Wang, Donghui Zhang, Huaqiang Chu
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Abstract

Biomass offers a promising alternative for producing biofuels and chemicals through hydrothermal liquefaction, a process known for its ability to convert complex organic materials into valuable liquid products. Optimizing hydrothermal liquefaction for large-scale application involves understanding the underlying mechanisms and addressing key scientific and technical issues. We review hydrothermal liquefaction of biomass-derived chemicals, focusing on the breakdown and depolymerization of cellulose, hemicellulose, lignin, lipids, and proteins under hydrothermal conditions. We examine critical parameters such as reaction temperature, pressure, solvent selection, and catalyst choice, and their impact on product yield and quality. Catalytic routes transform key intermediates, such as 5-hydroxymethylfurfural and levulinic acid, into high-value liquid fuels and chemicals, offering significant potential for sustainable fuel production. Recent advances in process optimization are discussed.

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水热液化法利用生物质衍生平台化合物生产液体燃料和化学品:综述
生物质为通过水热液化生产生物燃料和化学品提供了一种前景广阔的替代方法,水热液化是一种以能够将复杂的有机材料转化为有价值的液体产品而著称的工艺。要优化水热液化以实现大规模应用,就必须了解其基本机制并解决关键的科学和技术问题。我们回顾了生物质衍生化学品的水热液化,重点是纤维素、半纤维素、木质素、脂质和蛋白质在水热条件下的分解和解聚。我们研究了反应温度、压力、溶剂选择和催化剂选择等关键参数及其对产品产量和质量的影响。催化路线可将 5- 羟甲基糠醛和乙酰丙酸等关键中间产物转化为高价值的液体燃料和化学品,为可持续燃料生产提供了巨大潜力。本文讨论了工艺优化方面的最新进展。
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来源期刊
Environmental Chemistry Letters
Environmental Chemistry Letters 环境科学-工程:环境
CiteScore
32.00
自引率
7.00%
发文量
175
审稿时长
2 months
期刊介绍: Environmental Chemistry Letters explores the intersections of geology, chemistry, physics, and biology. Published articles are of paramount importance to the examination of both natural and engineered environments. The journal features original and review articles of exceptional significance, encompassing topics such as the characterization of natural and impacted environments, the behavior, prevention, treatment, and control of mineral, organic, and radioactive pollutants. It also delves into interfacial studies involving diverse media like soil, sediment, water, air, organisms, and food. Additionally, the journal covers green chemistry, environmentally friendly synthetic pathways, alternative fuels, ecotoxicology, risk assessment, environmental processes and modeling, environmental technologies, remediation and control, and environmental analytical chemistry using biomolecular tools and tracers.
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