Fluorescence spectroscopy combined with multilayer perceptron deep learning to identify the authenticity of monofloral honey—Rape honey

Shengkang Ji , Shengyu Hao , Jie Yuan , Hongzhuan Xuan
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Abstract

Honey authenticity is critical to honey quality. The development of a quick, easy, and non-destructive technique for determining the authenticity of honey encourages an improvement in honey quality. Here, the authenticity of monofloral honey—rape honey was determined using fluorescence spectroscopy combined with multilayer perceptron (MLP) deep learning, without the need for any prior feature extraction or pre-processing. A total of 91 raw fluorescence intensity data of the real and adulterated honey samples at a fixed excitation wavelength of 280 nm were first matrixed, and all data were then categorized into a training set, a validation set, and a test set with numbers of 64, 16, and 11, respectively. The connection with dropout was selected to build and link the MLP internal network. The activation function, learning rate, optimizer, and number of epochs were among the hyperparameters of the MLP neural network that were tuned. A good MLP deep learning network model for determining the authenticity of monofloral honey, rape honey, was developed after constant validation and debugging. According to the accuracy curve of the MLP model, the accuracy of the training set increased with the number of epochs and eventually converged to 100 %, while the accuracy of the validation set could be well stabilized at about 100 % after 5000 epochs. Finally, the accuracy of the MLP model on the test set was close to 100 %. According to our findings, the MLP neural network and fluorescence intensity have great potential applications in identifying the authenticity of honey.

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荧光光谱与多层感知器深度学习相结合,识别单花蜜-油菜花蜜的真伪。
蜂蜜的真伪对蜂蜜质量至关重要。开发一种快速、简便、无损的蜂蜜真伪鉴别技术有助于提高蜂蜜质量。在此,我们利用荧光光谱与多层感知器(MLP)深度学习相结合的方法来确定单花蜜-葡萄蜜的真伪,而无需事先进行任何特征提取或预处理。首先对真蜂蜜和掺假蜂蜜样品在固定激发波长 280 nm 下的共 91 个原始荧光强度数据进行矩阵化,然后将所有数据分为训练集、验证集和测试集,其数量分别为 64、16 和 11。MLP 内部网络的建立和连接选择了带 dropout 的连接。MLP 神经网络的超参数包括激活函数、学习率、优化器和历时次数。经过不断的验证和调试,建立了一个良好的 MLP 深度学习网络模型,用于判断单花蜜--油菜蜜的真伪。根据MLP模型的准确率曲线,训练集的准确率随着epoch次数的增加而增加,最终收敛到100%,而验证集的准确率在5000个epoch后可以很好地稳定在100%左右。最后,MLP 模型在测试集上的准确率接近 100%。根据我们的研究结果,MLP 神经网络和荧光强度在鉴别蜂蜜真伪方面具有很大的应用潜力。
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来源期刊
CiteScore
8.40
自引率
11.40%
发文量
1364
审稿时长
40 days
期刊介绍: Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy (SAA) is an interdisciplinary journal which spans from basic to applied aspects of optical spectroscopy in chemistry, medicine, biology, and materials science. The journal publishes original scientific papers that feature high-quality spectroscopic data and analysis. From the broad range of optical spectroscopies, the emphasis is on electronic, vibrational or rotational spectra of molecules, rather than on spectroscopy based on magnetic moments. Criteria for publication in SAA are novelty, uniqueness, and outstanding quality. Routine applications of spectroscopic techniques and computational methods are not appropriate. Topics of particular interest of Spectrochimica Acta Part A include, but are not limited to: Spectroscopy and dynamics of bioanalytical, biomedical, environmental, and atmospheric sciences, Novel experimental techniques or instrumentation for molecular spectroscopy, Novel theoretical and computational methods, Novel applications in photochemistry and photobiology, Novel interpretational approaches as well as advances in data analysis based on electronic or vibrational spectroscopy.
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