Impact of vanadium (V) content on in-situ oxidation, high temperature mechanical strength and tribological properties of Al0.5CrFeNiVx high entropy alloys

IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Tribology International Pub Date : 2024-11-08 DOI:10.1016/j.triboint.2024.110375
Xiaotian Wu , Lihong Su , Anh Kiet Tieu , Jun Cheng , Cuong Nguyen , Hongtao Zhu , Jun Yang , Guanyu Deng
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Abstract

In this study, four vanadium (V) containing high entropy alloys (HEAs) Al0.5CrFeNiVx (x = 0.25, 0.5, 0.75, 1.0) were developed and investigated, in terms of examining the influence of V content on their microstructure, in-situ oxidation behavior, high temperature mechanical strength, and high temperature tribological performances. An increase in the V content causes precipitation of the Laves phase (VAl2) in the body-centered cubic (BCC) matrix. This structural transition increases the alloy hardness and compressive strength through solid solution strengthening, precipitation strengthening and grain refinement strengthening. When x is increased from 0.25 to 1, the maximum compressive strength increases from about 2476 to 3241 MPa at room temperature and from about 521 to 797 MPa at 700 °C, respectively. In-situ oxidation investigation reveals that a higher V content accelerates the oxidation and provides a direct evidence of vanadium oxides melting at 700 °C and thus forming the liquid oxide phases on the surface of HEAs. During high temperature tribological contact, the liquid oxide phases minimize the friction, allowing thicker and more complex oxide layers to form on the worn surface to improve the HEAs’ wear resistance. The findings in this work contribute to the development of novel HEAs with superior properties for potential applications that need outstanding mechanical strength, wear resistance, and thermal stability.
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钒 (V) 含量对 Al0.5CrFeNiVx 高熵合金的原位氧化、高温机械强度和摩擦学性能的影响
本研究开发了四种含钒(V)的高熵合金(HEAs)Al0.5CrFeNiVx(x = 0.25、0.5、0.75、1.0),并研究了钒含量对其微观结构、原位氧化行为、高温机械强度和高温摩擦学性能的影响。钒含量的增加会导致体心立方(BCC)基体中的拉维斯相(VAl2)析出。这种结构转变通过固溶强化、沉淀强化和晶粒细化强化提高了合金的硬度和抗压强度。当 x 从 0.25 增加到 1 时,室温下的最大抗压强度从 2476 兆帕增加到 3241 兆帕,700 °C 时的最大抗压强度从 521 兆帕增加到 797 兆帕。原位氧化研究表明,钒含量越高,氧化速度越快,并直接证明钒氧化物在 700 ℃ 下熔化,从而在 HEA 表面形成液态氧化物相。在高温摩擦接触过程中,液态氧化物相会将摩擦降到最低,从而在磨损表面形成更厚、更复杂的氧化层,提高 HEAs 的耐磨性。这项研究成果有助于开发具有优异性能的新型 HEA,以满足需要出色机械强度、耐磨性和热稳定性的潜在应用。
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来源期刊
Tribology International
Tribology International 工程技术-工程:机械
CiteScore
10.10
自引率
16.10%
发文量
627
审稿时长
35 days
期刊介绍: Tribology is the science of rubbing surfaces and contributes to every facet of our everyday life, from live cell friction to engine lubrication and seismology. As such tribology is truly multidisciplinary and this extraordinary breadth of scientific interest is reflected in the scope of Tribology International. Tribology International seeks to publish original research papers of the highest scientific quality to provide an archival resource for scientists from all backgrounds. Written contributions are invited reporting experimental and modelling studies both in established areas of tribology and emerging fields. Scientific topics include the physics or chemistry of tribo-surfaces, bio-tribology, surface engineering and materials, contact mechanics, nano-tribology, lubricants and hydrodynamic lubrication.
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