High strength and high ductility Mg-Gd-Y-Zn-Zr alloys obtained by controlling texture and dynamic precipitation through LPSO phase structure of different initial morphologies

IF 5.2 1区 化学 Q1 CHEMISTRY, APPLIED Journal of Rare Earths Pub Date : 2024-06-29 DOI:10.1016/j.jre.2024.06.042
Yayun He , Rui Guo , Xi Zhao , Zhimin Zhang
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Abstract

This paper investigated the effects of three different initial phase structures on the microstructure evolution and tensile properties of extruded Mg-Gd-Y-Zn-Zr alloy, using an extrusion ratio of 3.6. These three initial phase structures were obtained by heat treatment, which is narrow spacing long-period stacking ordered phase (LPSO) phase structure alloy (EN alloy), wide spacing LPSO phase structure alloy (EW alloy), and narrow spacing LPSO phase and β phase overlapping phase structure alloy (EO alloy). The dynamic recrystallization (DRX) and dynamic precipitation behavior of extruded alloys with different initial structures, as well as their strengthening and ductility mechanisms were studied in detail. After hot extrusion with a low extrusion ratio, the alloy exhibits a bimodal structure composed of undynamic recrystallization (UN-DRX) grains and dynamic recrystallization (DRX) grains with strong textures. The narrow-spacing LPSO phase structure inhibits DRX and dynamic precipitation, while both the wide-spacing LPSO phase structure and the overlapping phase structure alloys promote DRX and dynamic precipitation. The strength improvement is mainly due to the strong texture and internal dislocation pinning of the undynamic recrystallization zone (UN-DRX) and the high strengthening effect of the narrow spacing LPSO phase. Although the promotion of DRX improves grain boundary strengthening effect, it cannot make up for reducing the UN-DRXed grain strengthening effect. A lower volume fraction of β dynamic precipitation phase is beneficial for improving the ductility of the alloy.

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通过控制不同初始形态的 LPSO 相结构的质地和动态沉淀获得高强度和高延展性 Mg-Gd-Y-Zn-Zr 合金
本文研究了挤压比为 3.6 时三种不同初始相结构对挤压 Mg-Gd-Y-Zn-Zr 合金微观结构演变和拉伸性能的影响。这三种初始相结构是通过热处理获得的,分别是窄间距长周期堆积有序相(LPSO)相结构合金(EN合金)、宽间距LPSO相结构合金(EW合金)和窄间距LPSO相与β相重叠相结构合金(EO合金)。详细研究了不同初始结构挤压合金的动态再结晶(DRX)和动态析出行为及其强化和延展机制。在低挤压比热挤压后,合金呈现出由非动态再结晶(UN-DRX)晶粒和具有强纹理的动态再结晶(DRX)晶粒组成的双峰结构。窄间距 LPSO 相结构抑制了 DRX 和动态析出,而宽间距 LPSO 相结构和重叠相结构合金则促进了 DRX 和动态析出。强度的提高主要得益于非动态再结晶区(UN-DRX)的强质地和内部位错钉扎以及窄间距 LPSO 相的高强化效果。虽然 DRX 的促进提高了晶界强化效果,但无法弥补 UN-DRX 晶界强化效果的降低。降低β动态析出相的体积分数有利于提高合金的延展性。
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来源期刊
Journal of Rare Earths
Journal of Rare Earths 化学-应用化学
CiteScore
8.70
自引率
14.30%
发文量
374
审稿时长
1.7 months
期刊介绍: The Journal of Rare Earths reports studies on the 17 rare earth elements. It is a unique English-language learned journal that publishes works on various aspects of basic theory and applied science in the field of rare earths (RE). The journal accepts original high-quality original research papers and review articles with inventive content, and complete experimental data. It represents high academic standards and new progress in the RE field. Due to the advantage of abundant RE resources of China, the research on RE develops very actively, and papers on the latest progress in this field emerge every year. It is not only an important resource in which technicians publish and obtain their latest research results on RE, but also an important way of reflecting the updated progress in RE research field. The Journal of Rare Earths covers all research and application of RE rare earths including spectroscopy, luminescence and phosphors, rare earth catalysis, magnetism and magnetic materials, advanced rare earth materials, RE chemistry & hydrometallurgy, RE metallography & pyrometallurgy, RE new materials, RE solid state physics & solid state chemistry, rare earth applications, RE analysis & test, RE geology & ore dressing, etc.
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