{"title":"Comparison of total phenolic content in organic and conventional carrot under different drying conditions using non-destructive analysis techniques","authors":"Aysel Arslan , Nafiz Çeliktaş , Yurtsever Soysal , Muharrem Keskin","doi":"10.1016/j.microc.2024.112279","DOIUrl":null,"url":null,"abstract":"<div><div>Current evidence indicates that the higher nutritional value of organic foods, compared to their conventional counterparts, significantly impacts consumer demand. However, the application of thermal processes during processing may lead to a loss of nutritional values, including total phenolics and antioxidants, thereby failing to meet consumer expectations. Phenolics, known as some of the most potent natural antioxidants and are typically assessed through biochemical tests based on the concentration and reactivity of antioxidant compounds. However, the extraction methods can affect the accuracy of phenolic content measurement. In this study, the total phenolic (TP) (mg/100 g) capacity of fresh, hot air (HA)-dried, and intermittent microwave (IMW)-dried organic and conventional black carrots were compared, and the detectability of these compounds using a colorimeter and FT-NIRS was evaluated. PLSR models developed for estimating the TP content using FT-NIRS resulted in successful outcomes (IMW: R<sup>2</sup><sub>val</sub> = 0.78, RMSEP = 51.4 mg/100 g; HA: R<sup>2</sup><sub>val</sub> = 0.70, RMSEP = 63.0 mg/100 g). The highest prediction accuracy was achieved with drying treatments at 300 W (R<sup>2</sup><sub>val</sub> = 0.95, RMSEP = 5.1 mg/100 g) and 450 W (R<sup>2</sup><sub>val</sub> = 0.83, RMSEP = 50.7 mg/100 g), as well as at 80 °C (R<sup>2</sup><sub>val</sub> = 0.90, RMSEP = 21.0 mg/100 g). The drying methods significantly influenced the TP content and the accuracy of TP prediction in samples. Additionally, organic carrots contained a higher level of total phenolic compared to conventional.</div></div>","PeriodicalId":391,"journal":{"name":"Microchemical Journal","volume":"208 ","pages":"Article 112279"},"PeriodicalIF":4.9000,"publicationDate":"2024-11-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Microchemical Journal","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0026265X24023919","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Current evidence indicates that the higher nutritional value of organic foods, compared to their conventional counterparts, significantly impacts consumer demand. However, the application of thermal processes during processing may lead to a loss of nutritional values, including total phenolics and antioxidants, thereby failing to meet consumer expectations. Phenolics, known as some of the most potent natural antioxidants and are typically assessed through biochemical tests based on the concentration and reactivity of antioxidant compounds. However, the extraction methods can affect the accuracy of phenolic content measurement. In this study, the total phenolic (TP) (mg/100 g) capacity of fresh, hot air (HA)-dried, and intermittent microwave (IMW)-dried organic and conventional black carrots were compared, and the detectability of these compounds using a colorimeter and FT-NIRS was evaluated. PLSR models developed for estimating the TP content using FT-NIRS resulted in successful outcomes (IMW: R2val = 0.78, RMSEP = 51.4 mg/100 g; HA: R2val = 0.70, RMSEP = 63.0 mg/100 g). The highest prediction accuracy was achieved with drying treatments at 300 W (R2val = 0.95, RMSEP = 5.1 mg/100 g) and 450 W (R2val = 0.83, RMSEP = 50.7 mg/100 g), as well as at 80 °C (R2val = 0.90, RMSEP = 21.0 mg/100 g). The drying methods significantly influenced the TP content and the accuracy of TP prediction in samples. Additionally, organic carrots contained a higher level of total phenolic compared to conventional.
期刊介绍:
The Microchemical Journal is a peer reviewed journal devoted to all aspects and phases of analytical chemistry and chemical analysis. The Microchemical Journal publishes articles which are at the forefront of modern analytical chemistry and cover innovations in the techniques to the finest possible limits. This includes fundamental aspects, instrumentation, new developments, innovative and novel methods and applications including environmental and clinical field.
Traditional classical analytical methods such as spectrophotometry and titrimetry as well as established instrumentation methods such as flame and graphite furnace atomic absorption spectrometry, gas chromatography, and modified glassy or carbon electrode electrochemical methods will be considered, provided they show significant improvements and novelty compared to the established methods.