Effect of Nb contents on the passivation behavior of high-strength anti-seismic rebar in concrete environments

IF 6.6 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY npj Materials Degradation Pub Date : 2024-11-29 DOI:10.1038/s41529-024-00543-w
Zeyun Zeng, Shangjun Gu, Jie Wang, Fulong Wei, Xiang Xie, Zhiying Li, Hui Yang, Changrong Li
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Abstract

In this study, the surface analysis, cross-section analysis and electrochemical analysis were used to explore the formation mechanism of Nb contents on the passive film of high-strength anti-seismic rebar in simulated concrete pore solution. The passivation experiments confirmed that the addition of Nb promoted the stability and compactness of surface passive film of Nb-containing rebar, and the passivation efficiency of Nb-containing rebar was stronger than that of CS rebar. Firstly, with the decreases of pH, the increases of Nb promoted that the outer layer of the passive film were mainly composed of Fe oxides and Fe oxyhydroxides, the inner layer were mainly composed of Fe oxides and Nb oxides. Secondly, the increases of Nb were beneficial to the formation of Nb oxides, which enhanced the passivation rate of the passive film and inhibited the degradation of Fe oxides, thus enhancing the thickness of surface passive film of Nb-containing rebar.

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Nb含量对混凝土环境中高强度抗震钢筋钝化性能的影响
本研究通过表面分析、截面分析和电化学分析,探讨了模拟混凝土孔隙溶液中高强度抗震钢筋被动膜上Nb含量的形成机理。钝化实验证实,Nb的加入促进了含Nb螺纹钢表面钝化膜的稳定性和致密性,且含Nb螺纹钢的钝化效率高于CS螺纹钢。首先,随着pH的降低,Nb的增加促使钝化膜外层主要由铁氧化物和铁氢氧化物组成,内层主要由铁氧化物和Nb氧化物组成。其次,Nb的增加有利于Nb氧化物的形成,从而提高了钝化膜的钝化速率,抑制了Fe氧化物的降解,从而提高了含Nb钢筋表面钝化膜的厚度。
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来源期刊
npj Materials Degradation
npj Materials Degradation MATERIALS SCIENCE, MULTIDISCIPLINARY-
CiteScore
7.80
自引率
7.80%
发文量
86
审稿时长
6 weeks
期刊介绍: npj Materials Degradation considers basic and applied research that explores all aspects of the degradation of metallic and non-metallic materials. The journal broadly defines ‘materials degradation’ as a reduction in the ability of a material to perform its task in-service as a result of environmental exposure. The journal covers a broad range of topics including but not limited to: -Degradation of metals, glasses, minerals, polymers, ceramics, cements and composites in natural and engineered environments, as a result of various stimuli -Computational and experimental studies of degradation mechanisms and kinetics -Characterization of degradation by traditional and emerging techniques -New approaches and technologies for enhancing resistance to degradation -Inspection and monitoring techniques for materials in-service, such as sensing technologies
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