Surface decoration of Nb2O5 hollow fibers by graphene oxide for enhanced photocatalytic degradation of methylene blue

IF 3.5 3区 材料科学 Q1 MATERIALS SCIENCE, CERAMICS Journal of the American Ceramic Society Pub Date : 2024-10-01 DOI:10.1111/jace.20176
Eduardo de Paulo Ferreira, Stella Rodrigues Ferreira Lima Ribeiro, Thiago Sousa e Sousa, Vicelma Luiz Cardoso, Miria Hespanhol Miranda Reis
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Abstract

This paper describes the fabrication of ceramic Nb2O5 hollow fibers covered by a thin graphene oxide (GO) layer using the vacuum-assisted dip-coating process for the efficient photocatalysis degradation of methylene blue (MB) under UVC light irradiation. Pristine and GO-coated Nb2O5 hollow fibers were evaluated for photocatalytic degradation at different initial dye concentrations and pH values. A photodegradation of 66.4% of the dye molecules was achieved using the pristine Nb2O5 hollow fibers at 57.4 ± 0.1 mg mL1, initial MB concentration of 10 mg L−1, and pH of 11. Under the same experimental conditions, the GO-coated Nb2O5 hollow fibers degraded 100% of the MB molecules. Additionally, the GO-coated Nb2O5 hollow fibers were successfully reused for four reaction cycles and exhibited suitable long-term stability. Thus, the proposed ceramic Nb2O5 hollow fibers with a surface decorated by a GO layer presented suitable characteristics for use as a photocatalyst in MB degradation.

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氧化石墨烯修饰Nb2O5中空纤维表面增强光催化降解亚甲基蓝
采用真空辅助浸包法制备了一层薄薄的氧化石墨烯(GO)覆盖的Nb2O5陶瓷中空纤维,用于UVC光下亚甲基蓝(MB)的高效光催化降解。在不同的初始染料浓度和pH值下,研究了原始和氧化石墨烯包覆Nb2O5中空纤维的光催化降解性能。在57.4±0.1 mg mL1,初始MB浓度为10 mg L−1,pH为11的条件下,原始Nb2O5中空纤维对染料分子的光降解率达到66.4%。在相同的实验条件下,氧化石墨烯包覆的Nb2O5中空纤维对MB分子的降解率为100%。此外,氧化石墨烯涂层的Nb2O5中空纤维成功地重复使用了四个反应周期,并表现出适当的长期稳定性。因此,所制备的表面有氧化石墨烯修饰的Nb2O5陶瓷中空纤维具有作为光催化剂降解MB的合适特性。
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来源期刊
Journal of the American Ceramic Society
Journal of the American Ceramic Society 工程技术-材料科学:硅酸盐
CiteScore
7.50
自引率
7.70%
发文量
590
审稿时长
2.1 months
期刊介绍: The Journal of the American Ceramic Society contains records of original research that provide insight into or describe the science of ceramic and glass materials and composites based on ceramics and glasses. These papers include reports on discovery, characterization, and analysis of new inorganic, non-metallic materials; synthesis methods; phase relationships; processing approaches; microstructure-property relationships; and functionalities. Of great interest are works that support understanding founded on fundamental principles using experimental, theoretical, or computational methods or combinations of those approaches. All the published papers must be of enduring value and relevant to the science of ceramics and glasses or composites based on those materials. Papers on fundamental ceramic and glass science are welcome including those in the following areas: Enabling materials for grand challenges[...] Materials design, selection, synthesis and processing methods[...] Characterization of compositions, structures, defects, and properties along with new methods [...] Mechanisms, Theory, Modeling, and Simulation[...] JACerS accepts submissions of full-length Articles reporting original research, in-depth Feature Articles, Reviews of the state-of-the-art with compelling analysis, and Rapid Communications which are short papers with sufficient novelty or impact to justify swift publication.
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