Enhanced Wear Resistance and Thermal Dissipation of Copper-Graphene Composite Coatings via Pulsed Electrodeposition for Circuit Breaker Applications.

Abstract

Copper, though highly conductive, requires improved wear resistance and thermal dissipation in applications that involve continuous movement and current-induced vibrations, such as power breakers. Conventional solutions, such as copper-tungsten alloys or lubricant use, face limitations in durability, friction, or environmental impact. This study explores the development of copper-graphene (Cu-GNPs) composite coatings using pulsed electrodeposition to enhance the tribological, thermal, and mechanical properties of circuit breaker components by adopting an industrially scalable technique. The influence of deposition bath temperature, duty cycle, and frequency on coating morphology, hardness, wear resistance, and heat dissipation was systematically evaluated using a 2³ full factorial design and an Analysis of Variance (ANOVA). The results revealed that optimized pulsed electrodeposition significantly improved coating performance: hardness increased by 76%, wear volume decreased by more than 99%, and friction coefficient stabilized at 0.2, reflecting effective graphene integration. The addition of graphene further improved thermal diffusivity by 19.5%, supporting superior heat dissipation. These findings suggest that pulsed copper-graphene composite coatings offer a promising alternative to traditional copper alloys, enhancing the lifespan and reliability of electronic components through improved wear resistance, lower friction, and superior heat transfer.