Historical inventories and future scenarios of multiple hazardous air pollutants (HAPs) emissions from the iron and steel production industry in China.

IF 8.2 1区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Science of the Total Environment Pub Date : 2025-01-01 Epub Date: 2024-12-20 DOI:10.1016/j.scitotenv.2024.178051
Junqi Yang, Hezhong Tian, Zhiqiang Fu, Xiaoxuan Bai, Kun Wang, Wenjun Liu, Yiping Lu, Yu Zhou, Hongyan Zhao, Jiangyu Cui, Qinwei Du
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Abstract

Iron and steel production (ISP) is one of significant atmospheric pollution emission sources in China. With the implementation of ultra-low emission (ULE) standards, a detailed and new updated emission inventory is urgently needed for better understanding of the temporal trends and spatial variation of emission characteristics. In this study, a unit-based comprehensive emission inventory of multiple hazardous air pollutants (HAPs) for the Chinese ISP spanned from 2012 to 2021, including the conventional pollutants, 13 kinds of Trace elements as well as 2 unconventional but toxic pollutants (PCDD/Fs, F), was dedicatedly developed by integrating dynamic localized emission factors with unit-based information of both the detailed activity level and abatement technology application. Scenario analyses were also conducted to forecast future emission trends up to 2050. The results showed that the lower emission factors owing to ULE retrofits had resulted in different spatial-temporal emission characteristics between outputs and HAPs emissions. The atmospheric emissions of SO2, NOX, PM2.5, PM10, TSP, F and PCDD/Fs from Chinese ISP in 2021 were estimated at about 414.4, 450.5, 1044.3, 2001.6, 3958.8, 9.42 kt and 9.35 kg-TEQ, respectively. And most HAPs emissions were lower than those in 2012. Regarding the spatial distribution, Hebei, Jiangsu, Shanxi, ranked as the top 3 emission provinces. Moreover, different manufacturing processes (sintering, blast furnace, steel making, etc.) contributed with different magnitude for specific species, and the future trends estimation showed a great reducing potential caused by the implementation of ULE abatement measures and structure adjustment in future.

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中国钢铁生产工业多种有害空气污染物排放的历史清单和未来情景。
钢铁生产是中国重要的大气污染排放源之一。随着超低排放标准的实施,迫切需要一个详细的、更新的排放清单,以便更好地了解排放特征的时间趋势和空间变化。本研究将动态局部排放因子与详细活动水平和减排技术应用的单元信息相结合,专门编制了2012 - 2021年中国ISP多种有害空气污染物(HAPs)基于单元的综合排放清单,包括常规污染物、13种微量元素以及2种非常规但有毒的污染物(PCDD/Fs, F)。并进行情景分析,预测至2050年的未来排放趋势。结果表明,由于ULE改造导致排放因子降低,导致产出与HAPs排放之间的时空特征不同。中国ISP在2021年的SO2、NOX、PM2.5、PM10、TSP、F和PCDD/Fs的大气排放量分别约为414.4、450.5、1044.3、2001.6、3958.8、9.42 kt和9.35 kg-TEQ。大多数HAPs的排放量低于2012年。空间分布上,河北、江苏、山西排在前3位。此外,不同的制造工艺(烧结、高炉、炼钢等)对特定物种的贡献程度不同,未来趋势预测显示,未来ULE减排措施的实施和结构调整将带来很大的减少潜力。
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来源期刊
Science of the Total Environment
Science of the Total Environment 环境科学-环境科学
CiteScore
17.60
自引率
10.20%
发文量
8726
审稿时长
2.4 months
期刊介绍: The Science of the Total Environment is an international journal dedicated to scientific research on the environment and its interaction with humanity. It covers a wide range of disciplines and seeks to publish innovative, hypothesis-driven, and impactful research that explores the entire environment, including the atmosphere, lithosphere, hydrosphere, biosphere, and anthroposphere. The journal's updated Aims & Scope emphasizes the importance of interdisciplinary environmental research with broad impact. Priority is given to studies that advance fundamental understanding and explore the interconnectedness of multiple environmental spheres. Field studies are preferred, while laboratory experiments must demonstrate significant methodological advancements or mechanistic insights with direct relevance to the environment.
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