Design of New Wet Heterogeneous Photo Oxidation Process for Refinery Waste Water Treatment in Photo Baffled Reactor

IF 3.8 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Water, Air, & Soil Pollution Pub Date : 2024-12-30 DOI:10.1007/s11270-024-07706-0
Yousif. S. Issa, Qahtan A. Mahmood, Jasim I. Humadi, Ghanim Hassan, Rajesh Haldhar
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Abstract

Phenol is considered as a hazardous agent in refinery waste water due to its toxicity to humans and animals. Therefore, numerous treatment processes are developed for removing this compound from industrial waste water which is an essential and important industrial need. In Baiji refinery-Iraq, the simulated produced wastewater with phenol concentration of 632 ppm represents a good example for examining a new application for removing this toxic agent. In this work, two different types of new heterogeneous catalyst were investigated and compared via catalytic wet photo oxidation process; namely, 5% ZnO/Al2O3 and 3% ZnO/Al2O3 as well as investigating temperature, reaction time, and mixing speed changes in photo baffled reactor. Results demonstrated that phenol removal efficiency proportional directly to reaction temperature, reaction duration, and mixing speed. A percentage of 95.45% Phenol removal was obtained using a temperature of 70 °C, reaction time of 100s, and a mixing speed of 750 rpm when using 5% ZnO/Al2O3. And when using 3% ZnO/Al2O3 the optimum removal was 86.22% with the same operating parameters. The new used technique proved to be a promising method for Phenol removal for industrial use in various applications.

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光折流板反应器处理炼油厂废水的湿式非均相光氧化新工艺设计
由于苯酚对人类和动物的毒性,它被认为是炼油厂废水中的一种有害物质。因此,开发了许多处理工艺来从工业废水中去除这种化合物,这是必不可少的和重要的工业需求。以伊拉克Baiji炼油厂632 ppm的苯酚模拟生产废水为例,研究了苯酚脱除的新应用。本文研究了两种不同类型的新型多相催化剂,并通过湿式光氧化法对其进行了比较;即5% ZnO/Al2O3和3% ZnO/Al2O3,并研究了光折流板反应器中温度、反应时间和混合速度的变化。结果表明,苯酚的去除率与反应温度、反应时间和混合速度成正比。当ZnO/Al2O3用量为5%时,反应温度为70℃,反应时间为100s,搅拌速度为750 rpm,苯酚去除率为95.45%。当ZnO/Al2O3用量为3%时,在相同的操作参数下,最佳去除率为86.22%。该技术在工业上具有广泛的应用前景。
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来源期刊
Water, Air, & Soil Pollution
Water, Air, & Soil Pollution 环境科学-环境科学
CiteScore
4.50
自引率
6.90%
发文量
448
审稿时长
2.6 months
期刊介绍: Water, Air, & Soil Pollution is an international, interdisciplinary journal on all aspects of pollution and solutions to pollution in the biosphere. This includes chemical, physical and biological processes affecting flora, fauna, water, air and soil in relation to environmental pollution. Because of its scope, the subject areas are diverse and include all aspects of pollution sources, transport, deposition, accumulation, acid precipitation, atmospheric pollution, metals, aquatic pollution including marine pollution and ground water, waste water, pesticides, soil pollution, sewage, sediment pollution, forestry pollution, effects of pollutants on humans, vegetation, fish, aquatic species, micro-organisms, and animals, environmental and molecular toxicology applied to pollution research, biosensors, global and climate change, ecological implications of pollution and pollution models. Water, Air, & Soil Pollution also publishes manuscripts on novel methods used in the study of environmental pollutants, environmental toxicology, environmental biology, novel environmental engineering related to pollution, biodiversity as influenced by pollution, novel environmental biotechnology as applied to pollution (e.g. bioremediation), environmental modelling and biorestoration of polluted environments. Articles should not be submitted that are of local interest only and do not advance international knowledge in environmental pollution and solutions to pollution. Articles that simply replicate known knowledge or techniques while researching a local pollution problem will normally be rejected without review. Submitted articles must have up-to-date references, employ the correct experimental replication and statistical analysis, where needed and contain a significant contribution to new knowledge. The publishing and editorial team sincerely appreciate your cooperation. Water, Air, & Soil Pollution publishes research papers; review articles; mini-reviews; and book reviews.
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