Electrochemical Detection of Hydrogen Peroxide at High Concentrations Using Hastelloy G35 Electrode

IF 3.7 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Langmuir Pub Date : 2025-01-12 DOI:10.1021/acs.langmuir.4c04757

Ala’a Mhmoued Abdllh Alboull, Hongzhan Liu, Fathimath Abbas, Altaf Hussain, Jieping Jiang, Baohua Lou, Guobao Xu

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Abstract

The detection of hydrogen peroxide (H₂O₂) at elevated concentrations while eliminating oxygen interference presents a significant challenge. Nickel-based stainless steel, such as Hastelloy G35, has shown excellent corrosion resistance. However, it has never been used in electroanalysis. In this study, the electrochemical analysis of H₂O₂ was conducted for the first time using nickel-based stainless steel electrode. The Hastelloy G35 electrode exhibited a very wide linear range from 1 up to 1000 mM and a detection limit of 0.0135 mM. The method is free from interference by oxygen. This method effectively detected H₂O₂ in skin wound wash solutions with excellent recoveries. The excellent performance of this method enhances its applicability in various fields, including industrial processes, environmental monitoring, and analytical chemistry, where quantifying concentrated H₂O₂ is of utmost importance. It shows that nickel-based stainless steel is promising for electroanalysis.

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来源期刊

Langmuir 化学-材料科学：综合

CiteScore

6.50

自引率

10.30%

发文量

1464

审稿时长

2.1 months

期刊介绍： Langmuir is an interdisciplinary journal publishing articles in the following subject categories: Colloids: surfactants and self-assembly, dispersions, emulsions, foams Interfaces: adsorption, reactions, films, forces Biological Interfaces: biocolloids, biomolecular and biomimetic materials Materials: nano- and mesostructured materials, polymers, gels, liquid crystals Electrochemistry: interfacial charge transfer, charge transport, electrocatalysis, electrokinetic phenomena, bioelectrochemistry Devices and Applications: sensors, fluidics, patterning, catalysis, photonic crystals However, when high-impact, original work is submitted that does not fit within the above categories, decisions to accept or decline such papers will be based on one criteria: What Would Irving Do? Langmuir ranks #2 in citations out of 136 journals in the category of Physical Chemistry with 113,157 total citations. The journal received an Impact Factor of 4.384*. This journal is also indexed in the categories of Materials Science (ranked #1) and Multidisciplinary Chemistry (ranked #5).