Facile synthesis of highly porous hierarchical ZnO nano-flowers array over graphene oxide nanocomposite for high performance Supercapacitor applications

IF 5.5 3区 材料科学 Q1 ELECTROCHEMISTRY Electrochimica Acta Pub Date : 2025-01-15 DOI:10.1016/j.electacta.2025.145676
R Aiswarya, T Kalaivani
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Abstract

Globalization, shifts in mobility, and digitization all contribute to an increase in energy use. Complex networks are now able to provide electricity at anytime and anywhere. However, there is a cost associated with this rise in energy use. Right present, there is an urgent energy demand for supercapacitors of high energy density. This study used the co-precipitation approach to synthesis hierarchical ZnO/GO in the form of flowers. The selection of ZnO/GO were based on its substantial electroactive surface area, shape resembling flowers, and effective pathways for electron transport and ion diffusion within the constructed hierarchical arrays. At 1 A/g, the GO-coated ZnO exhibits a capacitance of around 683.21 F/g. Fundamental investigations have proven that a synergistic impact between the hierarchical ZnO/GO nano-flower and GO nano-sheets helps to large surface area & outstanding transport characteristics. As a result, when used as an electrode in supercapacitors has more active sites and intercalation of ions, ZnO/GO hierarchical structures have shown an exceptional specific capacitance of 683.21 F/g at 1 A/g. Besides, it demonstrated excellent stability, holding onto its 74.047 % capacitance at 1 A/g even after 5000 cycles. These excellent electrochemical outcomes suggest that ZnO/GO is a good choice for energy storage uses.

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基于氧化石墨烯纳米复合材料的高孔层叠ZnO纳米花阵列的简单合成及其在高性能超级电容器中的应用
全球化、流动性变化和数字化都导致了能源使用的增加。现在,复杂的网络能够随时随地提供电力。然而,能源使用量的增加需要付出代价。目前,能源急需高能量密度的超级电容器。本研究采用共沉淀法合成了花朵状的分层 ZnO/GO。ZnO/GO 的选择基于其巨大的电活性表面积、类似花朵的形状以及在构建的分层阵列中电子传输和离子扩散的有效路径。在 1 A/g 的条件下,GO 涂层氧化锌的电容约为 683.21 F/g。基础研究证明,分层 ZnO/GO 纳米花和 GO 纳米片之间的协同作用有助于获得大表面积和出色的传输特性。因此,在超级电容器中用作电极时,ZnO/GO 层状结构具有更多的活性位点和离子插层,在 1 A/g 时显示出 683.21 F/g 的优异比电容。此外,它还表现出了极佳的稳定性,在 1 A/g 循环后仍能保持 74.047 % 的电容量。这些优异的电化学结果表明,ZnO/GO 是储能用途的良好选择。
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来源期刊
Electrochimica Acta
Electrochimica Acta 工程技术-电化学
CiteScore
11.30
自引率
6.10%
发文量
1634
审稿时长
41 days
期刊介绍: Electrochimica Acta is an international journal. It is intended for the publication of both original work and reviews in the field of electrochemistry. Electrochemistry should be interpreted to mean any of the research fields covered by the Divisions of the International Society of Electrochemistry listed below, as well as emerging scientific domains covered by ISE New Topics Committee.
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