Advances in copper nanocrystals: Synthesis, anti-oxidation strategies, and multiple applications

IF 20.3 1区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Coordination Chemistry Reviews Pub Date : 2025-01-17 DOI:10.1016/j.ccr.2025.216455
Ze-Xian Chen, Yuan-Jun Song, Ruo-Zhou Li, Si-Jie Guo, Lei Shi, Zong-Ru Yang, Xiao-Mei Xue, Tong Zhang
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Abstract

In recent years, copper (Cu) nanocrystals have garnered increasing interest in the field of metallic nanomaterials due to their low cost and excellent optical and electrical properties, positioning them as viable alternatives to noble metals such as Au and Ag. However, their susceptibility to oxidation in ambient conditions poses challenges for synthesis and practical applications. To address this, various anti-oxidation strategies have been developed, each offering distinct advantages. Despite growing research interest, a comprehensive review encompassing the synthesis, anti-oxidation strategies, and applications of Cu nanocrystals is currently lacking. This review systematically explores the preparation and shape-control techniques for Cu nanocrystals, covering diverse morphologies such as nanoparticles, nanowires, and nanosheets. It also provides an in-depth overview of existing anti-oxidation strategies, including surface capping and modification. Furthermore, the review highlights the multiple applications of Cu nanocrystals in optical and electrical domains, such as photocatalysis, electrocatalysis, sensing, luminescence, transparent conductive films, and nano-sintering. By elucidating the fundamental principles and mechanisms underlying each aspect, this review aims to offer comprehensive guidance for advancing research on Cu nanocrystals. Finally, it discusses the remaining challenges and future perspectives to enhance the applicability of Cu nanocrystals across various fields.

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铜纳米晶体的研究进展:合成、抗氧化策略及多种应用
近年来,铜(Cu)纳米晶体由于其低成本和优异的光学和电学性能而在金属纳米材料领域引起了越来越多的兴趣,将其定位为贵金属(如Au和Ag)的可行替代品。然而,它们在环境条件下的易氧化性给合成和实际应用带来了挑战。为了解决这个问题,各种抗氧化策略已经被开发出来,每种策略都有其独特的优势。尽管对铜纳米晶体的研究兴趣日益浓厚,但目前还缺乏对其合成、抗氧化策略和应用的全面综述。本文系统地探讨了铜纳米晶体的制备和形状控制技术,包括纳米颗粒、纳米线和纳米片等多种形态。它还提供了现有抗氧化策略的深入概述,包括表面封盖和改性。此外,综述了铜纳米晶体在光催化、电催化、传感、发光、透明导电膜和纳米烧结等光电领域的应用。本文旨在通过对各个方面的基本原理和机制的阐述,为Cu纳米晶体的进一步研究提供全面的指导。最后,讨论了提高Cu纳米晶体在各个领域的适用性所面临的挑战和未来的展望。
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来源期刊
Coordination Chemistry Reviews
Coordination Chemistry Reviews 化学-无机化学与核化学
CiteScore
34.30
自引率
5.30%
发文量
457
审稿时长
54 days
期刊介绍: Coordination Chemistry Reviews offers rapid publication of review articles on current and significant topics in coordination chemistry, encompassing organometallic, supramolecular, theoretical, and bioinorganic chemistry. It also covers catalysis, materials chemistry, and metal-organic frameworks from a coordination chemistry perspective. Reviews summarize recent developments or discuss specific techniques, welcoming contributions from both established and emerging researchers. The journal releases special issues on timely subjects, including those featuring contributions from specific regions or conferences. Occasional full-length book articles are also featured. Additionally, special volumes cover annual reviews of main group chemistry, transition metal group chemistry, and organometallic chemistry. These comprehensive reviews are vital resources for those engaged in coordination chemistry, further establishing Coordination Chemistry Reviews as a hub for insightful surveys in inorganic and physical inorganic chemistry.
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