Disturbance-Triggered Instant Crystallization Activating Bioinspired Emissive Gels

Abstract

Many marine organisms feature sensitive sensory-perceptual systems to sense the surrounding environment and respond to disturbance with intense bioluminescence. However, it remains a great challenge to develop artificial materials that can sense external disturbance and simultaneously activate intense luminescence, although such materials are attractive for visual sensing and intelligent displays. Herein, we present a new class of bioinspired smart gels constructed by integrating hydrophilic polymeric networks, metastable supersaturated salt and fluorophores containing heterogenic atoms. Upon external disturbance, the composite gels undergo an instant and reversible soft-rigid state transition, simultaneously turning on intense fluorescence and activating ultralong afterglow emission with a maximum lifetime of 877.15 ms. The experimental results and molecular dynamics simulations reveal that the disturbance-induced luminescence mainly results from the geometrical confinement of aggregated fluorophores and enhanced molecular interactions to immensely suppress the non-radiative dissipation. Given their versatile and sensitive disturbance-responsiveness, dynamic interactive painting and 3D smart optical displays are demonstrated. This study paves a new avenue to achieve disturbance-sensing soft materials and promotes the development of smart visual sensors and interactive optical displays.