CNSL-based plasticizers, a promising and sustainable alternative to phthalates, a review

A. Gartili, V. Lapinte, S. Caillol, B. Briou and L. Jego
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Abstract

With growing environmental concerns and the depletion of petrochemical resources, biomass-derived chemicals have garnered significant attention. Biomass-derived plasticizers have been widely studied as alternatives to toxic petroleum-based plasticizers. However, the bioressources used for their synthesis, an inedible oil derived from agricultural waste, containing cardanol, cardol and anacardic acid, is attracting new interest. Recent research has focused on cardanol-based plasticizers for various polymers such as PVC, PLA, AC and rubber. Cardanol-based biobased plasticizers offer advantages such as renewability, solvent-resistant extraction and efficient plasticizing performance, making them potentially suitable for partial or total replacement of petroleum-based plasticizers. In this study, we discuss the different types of cardanol-based plasticizers according to their chemical structure, functional groups and applications in polymers. The aim of this study is to increase the interest of researchers in biobased plasticizers based on CNSL derivatives.

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基于cnsl的增塑剂——邻苯二甲酸酯的一种有前途的可持续替代品
随着环境问题的日益严重和石油化工资源的枯竭,生物质衍生化学品引起了人们的极大关注。生物质衍生增塑剂作为有毒石油基增塑剂的替代品已被广泛研究。然而,用于合成它们的生物资源,一种从农业废物中提取的不可食用油,含有腰果酚、腰果酚和心梗酸,正在引起新的兴趣。最近的研究主要集中在以腰果酚为基础的各种聚合物增塑剂,如PVC、PLA、AC和橡胶。腰果酚类生物增塑剂具有可再生、耐溶剂萃取和高效增塑剂性能等优点,有可能部分或全部替代石油基增塑剂。本文根据腰果酚类增塑剂的化学结构、官能团及其在聚合物中的应用,对其进行了综述。本研究的目的是增加研究人员对基于CNSL衍生物的生物基增塑剂的兴趣。
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Inside back cover Back cover Afterglow quenching in plasma-based dry reforming of methane: a detailed analysis of the post-plasma chemistry via kinetic modelling. Showcasing the technological advancements of carbon dioxide conversion: a pathway to a sustainable future From lead–acid batteries to perovskite solar cells – efficient recycling of Pb-containing materials†
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