Achieving flexible higher efficiency GaInP/GaAs/InGaAs solar cells by 40-period quantum well superlattices

IF 17.1 1区 材料科学 Q1 CHEMISTRY, PHYSICAL Nano Energy Pub Date : 2025-04-01 Epub Date: 2025-01-25 DOI:10.1016/j.nanoen.2025.110718
Menglu Yu , Junhua Long , Qiangjian Sun , Zhitao Chen , Xiaoxu Wu , Zhenlong Wu , Xiaolong Luo , Qing Gong , Wencong Yan , Qi Chen , Jianjun Zhu , Shulong Lu
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Abstract

Quantum-well tandem solar cells have been shown to achieve higher efficiencies due to a more matched bandgap combination. But beyond 100-period quantum wells, the stress balance of the epitaxial layer will become extremely difficult, especially for large-sized epitaxial layers. In this paper, a more economical 40-period InGaAs/GaAsP quantum well superlattices are used to achieve excellent spectral control of 8 cm2 GaInP/GaAs/InGaAs solar cells. Under the AM0 spectrum, the short-circuit current density of the triple-junction solar cells increased from 16.859 mA/cm2 to 17.665 mA/cm2, benefiting from the external quantum efficiency of approximately 40 % in the expanded spectral band of the 40-period quantum wells. Compared with conventional flexible GaInP/GaAs/InGaAs solar cells, the addition of 40-period quantum wells increased the efficiency from 32.30 % to 33.47 % (AM0). The 40-period quantum well superlattices is an effective parameter to achieve higher efficiency and large-area flexible triple-junction solar cells.

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利用40周期量子阱超晶格实现灵活高效的GaInP/GaAs/InGaAs太阳能电池
量子阱串联太阳能电池由于更匹配的带隙组合而显示出更高的效率。但超过100周期量子阱后,外延层的应力平衡将变得极其困难,特别是对于大尺寸外延层。本文采用更经济的40周期InGaAs/GaAsP量子阱超晶格,实现了8 cm2 GaInP/GaAs/InGaAs太阳能电池的优异光谱控制。在AM0光谱下,三结太阳能电池的短路电流密度从16.859 mA/cm2增加到17.665 mA/cm2,这得益于40周期量子阱扩展谱带中约40%的外量子效率。与传统的柔性GaInP/GaAs/InGaAs太阳能电池相比,40周期量子阱的加入使效率从32.30%提高到33.47% (AM0)。40周期量子阱超晶格是实现高效率、大面积柔性三结太阳能电池的有效参数。
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来源期刊
Nano Energy
Nano Energy CHEMISTRY, PHYSICAL-NANOSCIENCE & NANOTECHNOLOGY
CiteScore
30.30
自引率
7.40%
发文量
1207
审稿时长
23 days
期刊介绍: Nano Energy is a multidisciplinary, rapid-publication forum of original peer-reviewed contributions on the science and engineering of nanomaterials and nanodevices used in all forms of energy harvesting, conversion, storage, utilization and policy. Through its mixture of articles, reviews, communications, research news, and information on key developments, Nano Energy provides a comprehensive coverage of this exciting and dynamic field which joins nanoscience and nanotechnology with energy science. The journal is relevant to all those who are interested in nanomaterials solutions to the energy problem. Nano Energy publishes original experimental and theoretical research on all aspects of energy-related research which utilizes nanomaterials and nanotechnology. Manuscripts of four types are considered: review articles which inform readers of the latest research and advances in energy science; rapid communications which feature exciting research breakthroughs in the field; full-length articles which report comprehensive research developments; and news and opinions which comment on topical issues or express views on the developments in related fields.
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