Cu-Ag/SBA-15 nano catalysts for the control of microorganisms in water

IF 4.1 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Nanoscale Research Letters Pub Date : 2025-01-27 DOI:10.1186/s11671-024-04176-5
Saidulu Ganji, Ramesh Kola, Kumaraswamy Gullapelli, Ramesh Martha
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Abstract

Because of their uniform and regular channels, adjustable pore size, large surface area, controllable wall composition, high hydrothermal stability, ease of functional modification, and good accessibility of larger reactant molecules, mesoporous siliceous SBA-15 is of excellent catalyst carrier that is highly versatile and has been used extensively to prepare a variety of supported catalysts with ideal catalytic properties. In this study, we report the synthesis, characterization, and catalytic application of Cu-Ag/ SBA-15 nanoalloy catalysts towards the control of microorganisms in drinking water has been reported. The Cu-Ag/SBA-15 nanoalloy catalysts with different molar mass ratio of copper to silver (Cu:Ag = 1: 0, 0.75: 0.25, 0.5: 0.5, 0.25: 0.75, 0: 1) keeping 1weight % total loading of copper and silver metals on SBA-15 support have been prepared by incipient wetness impregnation method and characterized by various characterization techniques like, low angle XRD, wide angle XRD, N2-physcisorption and scanning electron microscopy techniques. The anti-bacterial activity of the catalysts was measured qualitatively by testing the presence of coliforms in water after contacting with the catalyst at room temperature. These nanoalloy catalysts found to be effective in controlling the microorganisms in drinking water. Among the series of the catalysts prepared, 0.25Cu-0.75Ag /SBA-15 catalyst showed superior catalytic activity. The high catalytic performance of the catalyst is due to its high surface area.

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Cu-Ag/SBA-15纳米催化剂对水中微生物控制的研究。
介孔硅质SBA-15具有通道均匀规则、孔径可调、比表面积大、壁组成可控、水热稳定性高、易于功能修饰、可接近较大反应物分子等特点,是一种通用性强的优良催化剂载体,被广泛用于制备各种负载型催化剂,具有理想的催化性能。在本研究中,我们报道了Cu-Ag/ SBA-15纳米合金催化剂的合成、表征及其在控制饮用水微生物中的催化应用。采用初湿浸渍法制备了铜银摩尔质量比(Cu:Ag = 1:0、0.75:0.25、0.5:0.5、0.25:0.75、0:1)不同铜银摩尔质量比(Cu:Ag = 1:0、0.75:0.25、0:1)的Cu-Ag/SBA-15纳米合金催化剂,并采用低角XRD、广角XRD、n2 -物理吸附、扫描电镜等多种表征技术对催化剂进行了表征。在室温下与催化剂接触后,通过测定水中大肠菌群的存在来定性地测定催化剂的抑菌活性。这些纳米合金催化剂对控制饮用水中的微生物有较好的效果。在所制备的系列催化剂中,0.25Cu-0.75Ag /SBA-15催化剂表现出较好的催化活性。催化剂的高催化性能是由于它的高表面积。
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来源期刊
Nanoscale Research Letters
Nanoscale Research Letters 工程技术-材料科学:综合
CiteScore
11.30
自引率
0.00%
发文量
110
审稿时长
48 days
期刊介绍: Nanoscale Research Letters (NRL) provides an interdisciplinary forum for communication of scientific and technological advances in the creation and use of objects at the nanometer scale. NRL is the first nanotechnology journal from a major publisher to be published with Open Access.
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