Evaluating low NOx hydrogen engines designed for off-road and construction applications.

IF 4.3 3区 环境科学与生态学 Q1 CHEMISTRY, ANALYTICAL Environmental Science: Processes & Impacts Pub Date : 2025-01-31 DOI:10.1039/d4em00448e
Lucy J Webster, Ryan Ballard, Tom Beamish, Tim Burnhope, Jack Humbert, Alastair C Lewis, Jakub Piaszyk, Sarah J Moller
{"title":"Evaluating low NO<sub><i>x</i></sub> hydrogen engines designed for off-road and construction applications.","authors":"Lucy J Webster, Ryan Ballard, Tom Beamish, Tim Burnhope, Jack Humbert, Alastair C Lewis, Jakub Piaszyk, Sarah J Moller","doi":"10.1039/d4em00448e","DOIUrl":null,"url":null,"abstract":"<p><p>Hydrogen internal combustion engines offer a near-term decarbonisation pathway for hard to electrify sectors such as non-road mobile machinery (NRMM). However, few hydrogen-specific engines have ever been developed with the twin-goals of maximising low carbon energy efficiency and delivering air quality co-benefits. We present analyses of dynamometer-derived nitrogen oxides (NO<sub><i>x</i></sub>) tailpipe emissions from four variants of a ∼55 kW four-cylinder port fuelled injection spark ignition hydrogen internal combustion engine (H2ICE) suitable for a range of uses within the NRMM industry. Engine out (pre-aftertreatment) emissions are also reported for one of the H2ICE variants. The emissions were compared over the Non-Road Transient Cycle (NRTC) with an equivalent contemporary Stage V emissions compliant 55 kW diesel engine. All four H2ICE variants were configured to operate under lean burn conditions generating substantially lower NO<sub><i>x</i></sub> exhaust emissions over the NRTC when compared to the diesel engine. Lowest NO<sub><i>x</i></sub> emissions were observed for a spark ignition H2ICE with selective catalytic reduction and particulate filter (SCRF) aftertreatment. Tailpipe NO<sub><i>x</i></sub> emissions over the full NRTC for this configuration were 1.90 mg kWh<sup>-1</sup>, a greater than 99% reduction compared to diesel (3340 mg kWh<sup>-1</sup>) with lower average NO<sub><i>x</i></sub> emissions observed for the H2ICEs over all power, torque, and speed settings. The frequency and magnitude of transient (<20 ms) increases in NO<sub><i>x</i></sub> were also compared between diesel and H2ICE. A H2ICE using a hydrogen slip catalyst, but without SCRF aftertreatment, also emitted significantly lower tailpipe NO<sub><i>x</i></sub> than the diesel equivalent (63.7 mg kWh<sup>-1</sup>), a factor of greater than 50 times improvement over the NRTC. This creates a systems level dilemma: whether the additional small absolute reductions in NO<sub><i>x</i></sub> achieved using SCRF would have a net benefit that outweighed the broader financial and environmental costs of the SCR and exhaust fluid manufacture, distribution and possible small in-service ammonia slip from exhaust. Irrespective of aftertreatment system, the adoption of low NO<sub><i>x</i></sub> emitting H2ICE in NRMM, and particularly construction equipment, would appear to offer much greater near-term air quality benefits for cities when compared to switching to other low carbon alternatives such as biodiesel or hydrotreated vegetable oil.</p>","PeriodicalId":74,"journal":{"name":"Environmental Science: Processes & Impacts","volume":" ","pages":""},"PeriodicalIF":4.3000,"publicationDate":"2025-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Environmental Science: Processes & Impacts","FirstCategoryId":"93","ListUrlMain":"https://doi.org/10.1039/d4em00448e","RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
引用次数: 0

Abstract

Hydrogen internal combustion engines offer a near-term decarbonisation pathway for hard to electrify sectors such as non-road mobile machinery (NRMM). However, few hydrogen-specific engines have ever been developed with the twin-goals of maximising low carbon energy efficiency and delivering air quality co-benefits. We present analyses of dynamometer-derived nitrogen oxides (NOx) tailpipe emissions from four variants of a ∼55 kW four-cylinder port fuelled injection spark ignition hydrogen internal combustion engine (H2ICE) suitable for a range of uses within the NRMM industry. Engine out (pre-aftertreatment) emissions are also reported for one of the H2ICE variants. The emissions were compared over the Non-Road Transient Cycle (NRTC) with an equivalent contemporary Stage V emissions compliant 55 kW diesel engine. All four H2ICE variants were configured to operate under lean burn conditions generating substantially lower NOx exhaust emissions over the NRTC when compared to the diesel engine. Lowest NOx emissions were observed for a spark ignition H2ICE with selective catalytic reduction and particulate filter (SCRF) aftertreatment. Tailpipe NOx emissions over the full NRTC for this configuration were 1.90 mg kWh-1, a greater than 99% reduction compared to diesel (3340 mg kWh-1) with lower average NOx emissions observed for the H2ICEs over all power, torque, and speed settings. The frequency and magnitude of transient (<20 ms) increases in NOx were also compared between diesel and H2ICE. A H2ICE using a hydrogen slip catalyst, but without SCRF aftertreatment, also emitted significantly lower tailpipe NOx than the diesel equivalent (63.7 mg kWh-1), a factor of greater than 50 times improvement over the NRTC. This creates a systems level dilemma: whether the additional small absolute reductions in NOx achieved using SCRF would have a net benefit that outweighed the broader financial and environmental costs of the SCR and exhaust fluid manufacture, distribution and possible small in-service ammonia slip from exhaust. Irrespective of aftertreatment system, the adoption of low NOx emitting H2ICE in NRMM, and particularly construction equipment, would appear to offer much greater near-term air quality benefits for cities when compared to switching to other low carbon alternatives such as biodiesel or hydrotreated vegetable oil.

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
求助全文
约1分钟内获得全文 去求助
来源期刊
Environmental Science: Processes & Impacts
Environmental Science: Processes & Impacts CHEMISTRY, ANALYTICAL-ENVIRONMENTAL SCIENCES
CiteScore
9.50
自引率
3.60%
发文量
202
审稿时长
1 months
期刊介绍: Environmental Science: Processes & Impacts publishes high quality papers in all areas of the environmental chemical sciences, including chemistry of the air, water, soil and sediment. We welcome studies on the environmental fate and effects of anthropogenic and naturally occurring contaminants, both chemical and microbiological, as well as related natural element cycling processes.
期刊最新文献
Evaluating low NOx hydrogen engines designed for off-road and construction applications. Photodegradation of typical psychotropic drugs in the aquatic environment: a critical review. Dissolved phosphorous through dry-wet-dry transitions in a small-dammed river basin: integrated understanding on transport patterns, export controls, and fate. Optical properties and photobleaching of wildfire ashes aqueous extracts. The INGENIOUS project: towards understanding air pollution in homes.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1