Front Cover: Redox Reactions of [RuIII(pic)3] (pic−=picolinate) with Sulfite in Aqueous Solution: Kinetic, and Mechanistic Studies (Eur. J. Inorg. Chem. 3/2025)

IF 2 4区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR European Journal of Inorganic Chemistry Pub Date : 2025-01-22 DOI:10.1002/ejic.202580301
Olga Impert, Debabrata Chatterjee
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Abstract

The Front Cover shows the redox reaction of a substitution-inert and electrically neutral [RuIII(pic)3] (pic=picolinate) complex with sulfite in aqueous solution. Studies revealed that, despite being a considerably more weakly electron-accepting oxidant than those reported previously for SIV oxidation, [RuIII(pic)3] can effectively and selectively oxidize sulfite to sulfate through an outer-sphere electron-transfer pathway. More information can be found in the Research Article by O. Impert and D. Chatterjee.

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封面:[RuIII(pic)3] (pic−=吡啶酸盐)与亚硫酸盐在水溶液中的氧化还原反应:动力学和机理研究。j . Inorg。化学3/2025)
前封面显示了取代惰性电中性[RuIII(pic)3] (pic−=吡啶酸盐)配合物与亚硫酸盐在水溶液中的氧化还原反应。研究表明,尽管与之前报道的SIV氧化相比,[RuIII(pic)3]是一种更弱的电子接受氧化剂,但它可以通过外球电子转移途径有效地选择性地将亚硫酸盐氧化为硫酸盐。更多信息可以在O. Impert和D. Chatterjee的研究文章中找到。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
European Journal of Inorganic Chemistry
European Journal of Inorganic Chemistry 化学-无机化学与核化学
CiteScore
4.30
自引率
4.30%
发文量
419
审稿时长
1.3 months
期刊介绍: The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry: Chemische Berichte Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.
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