Enhancing electrochemical performance of vanadium-doped ZnO nanoparticles based supercapacitor

Abstract

Metal-ion-doped transition metal oxides (TMOs) are suggested as innovative electrode materials with excellent cycling efficiency for asymmetric supercapacitors (ASCs). Here, we use a hydrothermal technique to synthesize vanadium (V) doped zinc oxide nanoparticles (NPs) as the electrode material for ASCs. The synthesized material pristine zinc oxide (ZO), 2 atomic% (at%) V-doped zinc oxide (2VZO), and 4 at% V-doped zinc oxide (4VZO) have been validated using various physical characterization techniques including XRD, FE-SEM, TGA, XPS, Raman, and FTIR techniques. The detailed electrochemical characterizations were performed, including CV, GCD, and EIS. The CV is investigated at the various scan rates, and GCD measurements are carried out to understand their charge-discharge characteristics at various current densities. The fabricated supercapacitor exhibits specific capacitance ($C_{sp}$) for ZO, 2VZO, and 4VZO are 71.53, 103.90, and 126.78 F g⁻¹ at 10 mV s⁻¹ scan rate, respectively. The 4VZO material-based device exhibits the maximum energy and power density ∼16 Wh kg⁻¹ and 4 kW kg⁻¹, respectively. The electrochemical impedance spectroscopy measurements are also carried out to understand the interface impedances and their impact on electrochemical performance.