Optimization of the perovskite cell in a bifacial two-terminal perovskite/silicon tandem module

IF 6.3 2区 材料科学 Q2 ENERGY & FUELS Solar Energy Materials and Solar Cells Pub Date : 2025-04-01 Epub Date: 2025-01-22 DOI:10.1016/j.solmat.2025.113431
Youri Blom, Malte Ruben Vogt, Olindo Isabella, Rudi Santbergen
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Abstract

Bifacial perovskite/silicon solar cells can combine the advantages of tandem technology (high efficiencies) and bifacial modules (additional received irradiance from the rear) to increase the energy yield of photovoltaic (PV) systems further. In literature, it has already been shown that for two-terminal tandems this would require a lower bandgap energy (Eg) for the perovskite cell, as the rear irradiance increases the current in the bottom cell creating a current mismatch, if this is not considered during optimization. This work expands on bifacial two-terminal tandem optimization by considering aspects not included before. Besides the Eg, the thickness (d) of the perovskite is also optimized, as this also affects the current matching. Additionally, this work studies the trends in different energy losses of the PV module to better understand what affects the optimal perovskite cell. Our simulations show that the optimal Eg is 1.61–1.65 eV and the optimal d is 650–750 nm, which agrees with the observations in literature. The optimal Eg and d are mostly a trade-off between mismatch and thermalization losses, meaning that the mismatch losses should not be fully minimized. Additionally, the irradiance from the rear side is converted less efficiently than the front side irradiance due to larger thermalization and reflection losses. Therefore, the energy yield of bifacial tandem modules, compared to monofacial tandem ones, only increases for large ground albedo. Finally, our results show that the bifacial tandems have over a 25% gain in energy yield compared to bifacial single junction modules and up to 5% gain compared to monofacial tandem modules.

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双面双端钙钛矿/硅串联模块中钙钛矿电池的优化
双面钙钛矿/硅太阳能电池可以结合串联技术(高效率)和双面模块(从后部额外接收辐照度)的优点,进一步提高光伏(PV)系统的能量产量。在文献中,已经表明,对于双端串联,这将需要较低的钙钛矿电池带隙能量(Eg),因为背面辐照度增加了底部电池的电流,从而产生电流不匹配,如果在优化过程中不考虑这一点。本工作通过考虑之前未包括的方面,扩展了双面双端串联优化。除了Eg外,钙钛矿的厚度(d)也进行了优化,因为这也会影响电流匹配。此外,本工作还研究了光伏组件不同能量损失的趋势,以更好地了解影响最佳钙钛矿电池的因素。模拟结果表明,最佳Eg为1.61 ~ 1.65 eV,最佳d为650 ~ 750 nm,与文献结果一致。最优的Eg和d主要是失配和热化损失之间的权衡,这意味着失配损失不应该完全最小化。此外,由于较大的热化和反射损失,后部的辐照度转换效率低于前部的辐照度。因此,与单面串联组件相比,双面串联组件的能量产率只有在地面反照率大的情况下才会增加。最后,我们的研究结果表明,与双面单结模块相比,双面串联模块的能量产量增加了25%以上,与单面串联模块相比,增益高达5%。
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来源期刊
Solar Energy Materials and Solar Cells
Solar Energy Materials and Solar Cells 工程技术-材料科学:综合
CiteScore
12.60
自引率
11.60%
发文量
513
审稿时长
47 days
期刊介绍: Solar Energy Materials & Solar Cells is intended as a vehicle for the dissemination of research results on materials science and technology related to photovoltaic, photothermal and photoelectrochemical solar energy conversion. Materials science is taken in the broadest possible sense and encompasses physics, chemistry, optics, materials fabrication and analysis for all types of materials.
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