Influence of sol-gel film on fusion bonded epoxy coatings on carbon steel: Surface, adhesion, mechanical, and corrosion protection characteristics in a saline medium

IF 6.3 3区 工程技术 Q1 ENGINEERING, CHEMICAL Journal of the Taiwan Institute of Chemical Engineers Pub Date : 2025-04-01 Epub Date: 2025-01-28 DOI:10.1016/j.jtice.2025.105994
A. Madhan Kumar , Rami K. Suleiman , M.A. Hussein , N.O. Ogunlakin
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Abstract

Background

Utilizing sol-gel film as an intermediate layer is considered one of the most fascinating routes to improving the overall efficiency of protective coatings. The current study aims to expand the surface protective performance of the fusion bonded epoxy (FBE) coating using deposited sol-gel films at the interface between the FBE and steel surface.

Methods

The structure, surface microstructure, and topography were characterized for prepared sol-gel films on carbon steel (CS). Also, contact angle measurements were performed to evaluate the surface free energy and wettability of the sol-gel coated CS substrates.

Significant findings

The adhesion test results showed that the CS surface with silane films enhanced the interfacial adhesion with the FBE, providing high adhesive strength for FBE coatings. The corrosion test results showed the improved anticorrosion performance of sol-gel deposited CS surface coated with FBE by showing high impedance values after one-month exposure. The achieved results confirmed that the CS with the sol-gel films significantly enhanced the surface energy by 2.7 times and improved surface hardness by 30 % compared with the bare and interfacial adhesion bonding of the subsequent FBE coating, and provided the improvement on the anticorrosion performance of FBE films in the saline medium.

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溶胶-凝胶膜对碳钢上熔合环氧涂层的影响:在盐水介质中的表面、附着力、机械和防腐特性
利用溶胶-凝胶膜作为中间层被认为是提高保护涂层整体效率的最有前途的途径之一。本研究旨在通过在FBE与钢表面之间的界面沉积溶胶-凝胶膜来扩大FBE涂层的表面保护性能。方法对碳钢(CS)表面制备的溶胶-凝胶膜的结构、表面微观结构和形貌进行表征。此外,通过接触角测量来评估溶胶-凝胶涂层CS基材的表面自由能和润湿性。附着力测试结果表明,CS表面硅烷膜增强了与FBE的界面附着力,为FBE涂层提供了较高的附着力。腐蚀试验结果表明,经FBE涂层的溶胶-凝胶沉积CS表面在暴露1个月后呈现出较高的阻抗值,防腐性能得到改善。研究结果证实,与随后的裸涂和界面粘接相比,溶胶-凝胶膜的CS表面能显著提高2.7倍,表面硬度提高30%,并改善了FBE膜在盐水介质中的防腐性能。
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来源期刊
CiteScore
9.10
自引率
14.00%
发文量
362
审稿时长
35 days
期刊介绍: Journal of the Taiwan Institute of Chemical Engineers (formerly known as Journal of the Chinese Institute of Chemical Engineers) publishes original works, from fundamental principles to practical applications, in the broad field of chemical engineering with special focus on three aspects: Chemical and Biomolecular Science and Technology, Energy and Environmental Science and Technology, and Materials Science and Technology. Authors should choose for their manuscript an appropriate aspect section and a few related classifications when submitting to the journal online.
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