Facile synthesis of porous SnO2@CuO nanosheets with highly sensitive performance of VOCs

IF 5.3 3区材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Materials Research Bulletin Pub Date : 2025-01-13 DOI:10.1016/j.materresbull.2025.113313

Haibo Ren , Jie Wan , Hui Pan , Jiarui Huang

{"title":"Facile synthesis of porous SnO2@CuO nanosheets with highly sensitive performance of VOCs","authors":"Haibo Ren , Jie Wan , Hui Pan , Jiarui Huang","doi":"10.1016/j.materresbull.2025.113313","DOIUrl":null,"url":null,"abstract":"<div><div>Porous SnO2/CuO nanosheets were prepared using a one-pot hydrothermal method. The samples were characterized using various analytical techniques. Additionally, porous SnO2 microflowers composed of uniform nanosheets were also produced. The specific surface areas (SSAs) of the porous SnO2/CuO nanosheets microcubes and the porous SnO2 microflowers were measured at 68.21 m2 g−1 and 11.91 m2 g−1, respectively. The porous SnO2/CuO nanosheets sensor displayed the superior sensing properties for isopropanol among the ten gases tested, achieving a maximum response of 51.76 towards 100 ppm isopropanol at an optimal working temperature. The response and recovery times for the SnO2/CuO sensor were recorded at 10 s and 14 s, respectively. Furthermore, the porous SnO2/CuO nanosheets sensor demonstrated excellent stability and repeatability over 28-day cycles, along with a low detection limit of 29 ppb. The combined benefits of the porous structure, larger SSA, and abundant p-n heterojunctions contributed to the enhanced sensing performance.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"185 ","pages":"Article 113313"},"PeriodicalIF":5.3000,"publicationDate":"2025-01-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Research Bulletin","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0025540825000212","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

Abstract

Porous SnO₂/CuO nanosheets were prepared using a one-pot hydrothermal method. The samples were characterized using various analytical techniques. Additionally, porous SnO₂ microflowers composed of uniform nanosheets were also produced. The specific surface areas (SSAs) of the porous SnO₂/CuO nanosheets microcubes and the porous SnO₂ microflowers were measured at 68.21 m² g⁻¹ and 11.91 m² g⁻¹, respectively. The porous SnO₂/CuO nanosheets sensor displayed the superior sensing properties for isopropanol among the ten gases tested, achieving a maximum response of 51.76 towards 100 ppm isopropanol at an optimal working temperature. The response and recovery times for the SnO₂/CuO sensor were recorded at 10 s and 14 s, respectively. Furthermore, the porous SnO₂/CuO nanosheets sensor demonstrated excellent stability and repeatability over 28-day cycles, along with a low detection limit of 29 ppb. The combined benefits of the porous structure, larger SSA, and abundant p-n heterojunctions contributed to the enhanced sensing performance.

Abstract Image

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

求助全文

约1分钟内获得全文去求助

来源期刊

Materials Research Bulletin 工程技术-材料科学：综合

CiteScore

9.80

自引率

5.60%

发文量

372

审稿时长

42 days

期刊介绍： Materials Research Bulletin is an international journal reporting high-impact research on processing-structure-property relationships in functional materials and nanomaterials with interesting electronic, magnetic, optical, thermal, mechanical or catalytic properties. Papers purely on thermodynamics or theoretical calculations (e.g., density functional theory) do not fall within the scope of the journal unless they also demonstrate a clear link to physical properties. Topics covered include functional materials (e.g., dielectrics, pyroelectrics, piezoelectrics, ferroelectrics, relaxors, thermoelectrics, etc.); electrochemistry and solid-state ionics (e.g., photovoltaics, batteries, sensors, and fuel cells); nanomaterials, graphene, and nanocomposites; luminescence and photocatalysis; crystal-structure and defect-structure analysis; novel electronics; non-crystalline solids; flexible electronics; protein-material interactions; and polymeric ion-exchange membranes.