Corrosion mechanisms of EH40 steel induced by extracellular polymeric substances from Halomonas titanicae cultivated under aerobic and anaerobic conditions

IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Corrosion Science Pub Date : 2025-04-15 Epub Date: 2025-01-31 DOI:10.1016/j.corsci.2025.112758
Mengyu Fu, Muqiu Xia, Li Lai, Shihang Lu, Shiqiang Chen, Guangzhou Liu
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Abstract

This study analyzed six extracellular polymeric substances (EPS) of Halomonas titanicae under aerobic (S-EPS, LB-EPS, TB-EPS) and anaerobic conditions (S-EPS', LB-EPS', TB-EPS'), investigating their corrosion impact on EH40 steel. Results indicate that S-EPS and S-EPS', primarily composed of humic acids and soluble microbial products, demonstrate an initial capacity for corrosion inhibition; however, this efficacy diminishes progressively with time. In contrast, protein-rich B-EPS and B-EPS' interact more strongly with the surface, particularly TB-EPS and TB-EPS', causing significant uneven corrosion. Furthermore, oxygen reduces EPS stability and interaction with steel, with corrosion effects more pronounced in anaerobic environments, especially for LB-EPS' and TB-EPS'.
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好氧和厌氧条件下培养的钛盐单胞菌胞外聚合物对EH40钢的腐蚀机理
本研究分析了钛盐单胞菌在好氧条件下(S-EPS、LB-EPS、TB-EPS)和厌氧条件下(S-EPS’、LB-EPS’、TB-EPS’)的6种胞外聚合物(EPS)对EH40钢的腐蚀影响。结果表明,S-EPS和S-EPS'主要由腐植酸和可溶性微生物产物组成,具有初步的缓蚀能力;然而,这种功效随着时间的推移逐渐减弱。相比之下,富含蛋白质的B-EPS和B-EPS与表面的相互作用更强,特别是TB-EPS和TB-EPS,造成明显的不均匀腐蚀。此外,氧气会降低EPS的稳定性和与钢的相互作用,在厌氧环境中,尤其是LB-EPS‘和TB-EPS’的腐蚀效果更为明显。
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来源期刊
Corrosion Science
Corrosion Science 工程技术-材料科学:综合
CiteScore
13.60
自引率
18.10%
发文量
763
审稿时长
46 days
期刊介绍: Corrosion occurrence and its practical control encompass a vast array of scientific knowledge. Corrosion Science endeavors to serve as the conduit for the exchange of ideas, developments, and research across all facets of this field, encompassing both metallic and non-metallic corrosion. The scope of this international journal is broad and inclusive. Published papers span from highly theoretical inquiries to essentially practical applications, covering diverse areas such as high-temperature oxidation, passivity, anodic oxidation, biochemical corrosion, stress corrosion cracking, and corrosion control mechanisms and methodologies. This journal publishes original papers and critical reviews across the spectrum of pure and applied corrosion, material degradation, and surface science and engineering. It serves as a crucial link connecting metallurgists, materials scientists, and researchers investigating corrosion and degradation phenomena. Join us in advancing knowledge and understanding in the vital field of corrosion science.
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