Lignin derived hard carbon for sodium ion batteries: Recent advances and future perspectives

IF 40 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Progress in Materials Science Pub Date : 2025-06-01 Epub Date: 2025-02-04 DOI:10.1016/j.pmatsci.2025.101452
Ao Wang , Gaoyue Zhang , Meng Li , Yuntong Sun , Yawen Tang , Kang Sun , Jong-Min Lee , Gengtao Fu , Jianchun Jiang
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Abstract

Lignin-derived hard carbon (LHC) is considered one of the most promising anode materials for sodium-ion batteries (SIBs) due to its abundant and renewable feedstocks, tunable microstructure, and excellent electrochemical performance. In recent years, significant progress has been achieved in the development of LHCs. However, a comprehensive review and critical evaluation of the existing research remain lacking, hindering their further advancement. To address this gap, this review first introduces the fundamental properties of lignin and hard carbon to elucidate the microstructural formation processes of LHCs. Subsequently, the fabrication methods and key characteristics of LHCs, along with the effects of feedstock properties and operating parameters on their microstructure and performance, are systematically summarized and analyzed. Particular attention is given to optimization strategies, including feedstock pretreatment, preparation process regulation, and post-treatment, to provide practical guidance for enhancing the overall performance of LHCs. Finally, suggestions and future perspectives for advancing LHCs in SIB applications are proposed based on the current research landscape and practical demands. This review aims to offer scientific insights into the microstructural regulation and electrochemical performance optimization of LHCs, thereby promoting their broader application in SIBs.

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钠离子电池用木质素衍生硬碳:最新进展和未来展望
木质素衍生硬碳(LHC)由于其丰富的可再生原料、可调节的微观结构和优异的电化学性能,被认为是钠离子电池(sib)最有前途的负极材料之一。近年来,lhc的发展取得了重大进展。然而,缺乏对现有研究的全面回顾和批判性评价,阻碍了它们的进一步发展。为了弥补这一空白,本文首先介绍了木质素和硬碳的基本性质,以阐明lhc的微观结构形成过程。随后,系统总结和分析了lhc的制备方法和关键特性,以及原料性质和操作参数对其微观结构和性能的影响。特别关注优化策略,包括原料预处理、制备工艺调节和后处理,为提高lhc的整体性能提供实用指导。最后,根据目前的研究现状和实际需求,提出了推进lhc在SIB应用的建议和未来展望。本文旨在为lhc的微观结构调控和电化学性能优化提供科学的见解,从而促进其在sib中的广泛应用。
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来源期刊
Progress in Materials Science
Progress in Materials Science 工程技术-材料科学:综合
CiteScore
59.60
自引率
0.80%
发文量
101
审稿时长
11.4 months
期刊介绍: Progress in Materials Science is a journal that publishes authoritative and critical reviews of recent advances in the science of materials. The focus of the journal is on the fundamental aspects of materials science, particularly those concerning microstructure and nanostructure and their relationship to properties. Emphasis is also placed on the thermodynamics, kinetics, mechanisms, and modeling of processes within materials, as well as the understanding of material properties in engineering and other applications. The journal welcomes reviews from authors who are active leaders in the field of materials science and have a strong scientific track record. Materials of interest include metallic, ceramic, polymeric, biological, medical, and composite materials in all forms. Manuscripts submitted to Progress in Materials Science are generally longer than those found in other research journals. While the focus is on invited reviews, interested authors may submit a proposal for consideration. Non-invited manuscripts are required to be preceded by the submission of a proposal. Authors publishing in Progress in Materials Science have the option to publish their research via subscription or open access. Open access publication requires the author or research funder to meet a publication fee (APC). Abstracting and indexing services for Progress in Materials Science include Current Contents, Science Citation Index Expanded, Materials Science Citation Index, Chemical Abstracts, Engineering Index, INSPEC, and Scopus.
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