Synergistic improvement of corrosion-strength of Al-Mg alloy by trace Sc/Zr and TiB2 particles

IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Corrosion Science Pub Date : 2025-04-15 Epub Date: 2025-02-01 DOI:10.1016/j.corsci.2025.112760
Xinchen Li , Kai Zhao , Xuekai Li , Bingzhi Li , Liyuan Yang , Enyu Guo , Huijun Kang , Zongning Chen , Tongmin Wang
{"title":"Synergistic improvement of corrosion-strength of Al-Mg alloy by trace Sc/Zr and TiB2 particles","authors":"Xinchen Li ,&nbsp;Kai Zhao ,&nbsp;Xuekai Li ,&nbsp;Bingzhi Li ,&nbsp;Liyuan Yang ,&nbsp;Enyu Guo ,&nbsp;Huijun Kang ,&nbsp;Zongning Chen ,&nbsp;Tongmin Wang","doi":"10.1016/j.corsci.2025.112760","DOIUrl":null,"url":null,"abstract":"<div><div>Intergranular corrosion (IGC) induced by the Mg-rich (β-Al<sub>3</sub>Mg<sub>2</sub>) precipitates in Al-Mg alloys during service presents significant safety risks and limits material development. Introducing trace Sc-Zr elements and TiB<sub>2</sub> particles into the alloy creates a dual heterostructure with abundant low-angle grain boundaries (LAGBs). The L1<sub>2</sub>-Al<sub>3</sub>(Sc,Zr) nano-precipitates inhibit recrystallization and stabilize the microstructure by pinning grain boundaries. TiB<sub>2</sub> particles refine the grain structure and promote LAGBs formation, reducing Mg-rich phase precipitation along grain boundaries. This alloy achieves high yield strength (∼381.5 MPa), elongation (∼11.2 %), and excellent IGC resistance, offering a novel approach to balancing mechanical properties and corrosion resistance in Al-Mg alloys.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"246 ","pages":"Article 112760"},"PeriodicalIF":7.4000,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Corrosion Science","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0010938X25000873","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2025/2/1 0:00:00","PubModel":"Epub","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

Abstract

Intergranular corrosion (IGC) induced by the Mg-rich (β-Al3Mg2) precipitates in Al-Mg alloys during service presents significant safety risks and limits material development. Introducing trace Sc-Zr elements and TiB2 particles into the alloy creates a dual heterostructure with abundant low-angle grain boundaries (LAGBs). The L12-Al3(Sc,Zr) nano-precipitates inhibit recrystallization and stabilize the microstructure by pinning grain boundaries. TiB2 particles refine the grain structure and promote LAGBs formation, reducing Mg-rich phase precipitation along grain boundaries. This alloy achieves high yield strength (∼381.5 MPa), elongation (∼11.2 %), and excellent IGC resistance, offering a novel approach to balancing mechanical properties and corrosion resistance in Al-Mg alloys.
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
微量Sc/Zr和TiB2粒子协同提高Al-Mg合金的腐蚀强度
在使用过程中,富mg (β-Al3Mg2)析出物引起的Al-Mg合金晶间腐蚀(IGC)存在重大的安全风险,并限制了材料的发展。在合金中引入微量Sc-Zr元素和TiB2颗粒,形成具有丰富的低角晶界(LAGBs)的双异质组织。L12-Al3(Sc,Zr)纳米相通过钉住晶界抑制再结晶,稳定微观组织。TiB2颗粒细化晶粒结构,促进LAGBs形成,减少晶界富mg相析出。该合金具有高屈服强度(~ 381.5 MPa)、伸长率(~ 11.2 %)和优异的抗IGC性能,为平衡Al-Mg合金的机械性能和耐腐蚀性提供了一种新的方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Corrosion Science
Corrosion Science 工程技术-材料科学:综合
CiteScore
13.60
自引率
18.10%
发文量
763
审稿时长
46 days
期刊介绍: Corrosion occurrence and its practical control encompass a vast array of scientific knowledge. Corrosion Science endeavors to serve as the conduit for the exchange of ideas, developments, and research across all facets of this field, encompassing both metallic and non-metallic corrosion. The scope of this international journal is broad and inclusive. Published papers span from highly theoretical inquiries to essentially practical applications, covering diverse areas such as high-temperature oxidation, passivity, anodic oxidation, biochemical corrosion, stress corrosion cracking, and corrosion control mechanisms and methodologies. This journal publishes original papers and critical reviews across the spectrum of pure and applied corrosion, material degradation, and surface science and engineering. It serves as a crucial link connecting metallurgists, materials scientists, and researchers investigating corrosion and degradation phenomena. Join us in advancing knowledge and understanding in the vital field of corrosion science.
期刊最新文献
Surface chemistry of carbon steel in contact with CO2 streams containing impurities An understanding of irradiation-assisted stress corrosion cracking of heavy ion-irradiated 321 stainless steel in high temperature and high pressure water Corrosion behavior and mechanisms of martensitic heat-resistant steel in high temperature H2O-CO2-H2S-H2 environments Phase composition and property evolution of high-entropy rare-earth disilicates with different average ionic radii as thermal / environmental barrier coating candidates A mechano-chemical investigation of SCC mitigation in pre-strained Alloy 600 in a simulated boiling water reactors environment with high oxygen concentrations
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1