Recent advances in potassium metal batteries: electrodes, interfaces and electrolytes.

Abstract

The exceptional theoretical capacity of potassium metal anodes (687 mA h g^-1), along with their low electrochemical potential, makes potassium metal batteries (PMBs) highly attractive for achieving high energy density. This review first provides an overview of potassium metal anodes, including their origin, current development status, and distinctive advantages compared to other metal anodes. Then, it discusses the composition and characteristics of emerging breakthrough PMBs, such as K-S, K-O₂, K-CO₂ batteries, and anode-free metal batteries. Subsequently, we delve into the pivotal challenges and theoretical research pertaining to PMBs, such as potassium metal nucleation/stripping, dendritic growth in PMBs, and unstable interfaces. Furthermore, we comprehensively examine the latest strategies in electrode design (including alloy, host, and current collector design), interface engineering (such as artificial solid electrolyte interphase layers, barrier layer design, and separator modification), and electrolyte optimization concerning nucleation, cycling stability, coulombic efficiency, and the development of PMBs. Finally, we introduce key characterization techniques, including in situ liquid phase secondary ion mass spectrometry, titration gas chromatography, neutron-based characterization, and computational simulation. This review will propel advancements in electrodes, separators, and electrolytes for innovative PMBs and other similar alkali metal batteries.