Controllable fabrication of high-quality magnetic nanofiber membranes using variable magnetic field-assisted electrospinning technology

IF 4.5 2区 化学 Q2 POLYMER SCIENCE Polymer Pub Date : 2025-03-12 Epub Date: 2025-02-08 DOI:10.1016/j.polymer.2025.128130
Jinghu Lv , Qihong Zhou , Gang Chen , Xiaoyue Guo , Chang Shu , Lihao Zhang , Shaoguo Zhou
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Abstract

This study introduces an innovative method for fabricating high-quality magnetic nanofiber membranes using controllable magnetic field-assisted electrospinning technology. By integrating electromagnetic lens technology, precise modulation of the magnetic field is achieved through current adjustments, effectively focusing charged particles during the electrospinning process. Furthermore, the interaction with magnetic nanoparticles enhances control over the nanofiber structure. Notably, the magnetic field generated by the electromagnetic lens adjusts the crystalline structure of PAN, resulting in a 19.2 % reduction in average fiber diameter, a 60.2 % decrease in deposited circular area, and a 50.8 % increase in average thickness. Additionally, significant improvements in magnetic properties are achieved, with a 56.5 % increase in saturated magnetization and a 200 % increase in coercivity. The crystalline and mechanical properties of the composites are also enhanced, indicating the great potential of this method for precise and controllable fabrication of magnetic nanofibers. This novel technology opens up new avenues for applications in sensors, filtration, and biomedical engineering.

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可变磁场辅助静电纺丝技术制备高品质磁性纳米纤维膜
本文介绍了一种利用可控磁场辅助静电纺丝技术制备高质量磁性纳米纤维膜的创新方法。结合电磁透镜技术,通过电流调节实现对磁场的精确调制,在静电纺丝过程中有效聚焦带电粒子。此外,与磁性纳米粒子的相互作用增强了对纳米纤维结构的控制。值得注意的是,电磁透镜产生的磁场调节了PAN的晶体结构,使PAN的平均纤维直径减小19.2%,沉积圆形面积减小60.2%,平均厚度增加50.8%。此外,磁性能也得到了显著改善,饱和磁化强度提高了56.5%,矫顽力提高了200%。复合材料的结晶性能和力学性能也得到了提高,这表明该方法在精确和可控的磁性纳米纤维制造方面具有巨大的潜力。这项新技术为传感器、过滤和生物医学工程的应用开辟了新的途径。
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来源期刊
Polymer
Polymer 化学-高分子科学
CiteScore
7.90
自引率
8.70%
发文量
959
审稿时长
32 days
期刊介绍: Polymer is an interdisciplinary journal dedicated to publishing innovative and significant advances in Polymer Physics, Chemistry and Technology. We welcome submissions on polymer hybrids, nanocomposites, characterisation and self-assembly. Polymer also publishes work on the technological application of polymers in energy and optoelectronics. The main scope is covered but not limited to the following core areas: Polymer Materials Nanocomposites and hybrid nanomaterials Polymer blends, films, fibres, networks and porous materials Physical Characterization Characterisation, modelling and simulation* of molecular and materials properties in bulk, solution, and thin films Polymer Engineering Advanced multiscale processing methods Polymer Synthesis, Modification and Self-assembly Including designer polymer architectures, mechanisms and kinetics, and supramolecular polymerization Technological Applications Polymers for energy generation and storage Polymer membranes for separation technology Polymers for opto- and microelectronics.
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