Adding Na2CO3 and repeated sintering enhancing red upconversion luminescence in GdLaO3:Er3+/Yb3+/Sc3+ under 980 nm laser excitation

IF 3.6 3区物理与天体物理 Q2 OPTICS Journal of Luminescence Pub Date : 2025-02-05 DOI:10.1016/j.jlumin.2025.121123

Meiling Li , Yongze Cao , Lihong Cheng , Yuhan Fan , Danyang Wu , Yichao Wang , Tianshuo Liu , Baojiu Chen

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Abstract

GdLaO₃(GLO):0.1Er³⁺/0.1 Yb³⁺/0.1Sc³⁺ phosphors were prepared by solid state sintering by adding Na₂CO₃. When the adding Na₂CO₃ is 0.05 mol%, the upconversion luminescence (UCL) intensity is the highest. In order to increase the brightness, we optimize the preparation process and carry out repeated sintering at 1500 °C. The samples repeatedly sintered four times have the highest UCL intensity. Under the 980 nm laser power density of 197.84 W/cm², the red UCL integral intensity of GLO:Er³⁺/Yb³⁺/Sc³⁺ is 1.1 times greater than that of β-NaYF₄:Er³⁺/Yb³⁺. This excellent UCL intensity is attributed to the shrinkage of the volume, the reduction of oxygen defects, and the increase of n in the multiphoton process. The maximum relative temperature sensitivity S_R is found to be 1.461 % K⁻¹ using the luminescence intensity ratio (LIR) technique. GLO:Er³⁺/Yb³⁺/Sc³⁺ has an outstanding pure red UCL intensity and can replace β-NaYF₄:Er³⁺/Yb³⁺ in applications such as luminescence display and temperature sensing.

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在980 nm激光激发下，加入Na2CO3和重复烧结增强了gdla3:Er3+/Yb3+/Sc3+的红色上转换发光

采用添加Na2CO3的固态烧结法制备了GdLaO3(GLO):0.1 er3 +/0.1 Yb3+/0.1 sc3 +荧光粉。Na2CO3添加量为0.05 mol%时，上转换发光强度最高。为了提高亮度，我们对制备工艺进行了优化，并在1500℃下进行了重复烧结。重复烧结4次的试样具有最高的UCL强度。在197.84 W/cm2的980 nm激光功率密度下，GLO:Er3+/Yb3+/Sc3+的红色UCL积分强度是β-NaYF4:Er3+/Yb3+的1.1倍。这种优异的UCL强度归因于多光子过程中体积的缩小、氧缺陷的减少和n的增加。利用发光强度比（LIR）技术，发现该材料的最大相对温度灵敏度SR为1.461% K−1。GLO:Er3+/Yb3+/Sc3+具有突出的纯红色UCL强度，可替代β-NaYF4:Er3+/Yb3+在发光显示和温度传感等应用中。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Journal of Luminescence 物理-光学

CiteScore

6.70

自引率

13.90%

发文量

850

审稿时长

3.8 months

期刊介绍： The purpose of the Journal of Luminescence is to provide a means of communication between scientists in different disciplines who share a common interest in the electronic excited states of molecular, ionic and covalent systems, whether crystalline, amorphous, or liquid. We invite original papers and reviews on such subjects as: exciton and polariton dynamics, dynamics of localized excited states, energy and charge transport in ordered and disordered systems, radiative and non-radiative recombination, relaxation processes, vibronic interactions in electronic excited states, photochemistry in condensed systems, excited state resonance, double resonance, spin dynamics, selective excitation spectroscopy, hole burning, coherent processes in excited states, (e.g. coherent optical transients, photon echoes, transient gratings), multiphoton processes, optical bistability, photochromism, and new techniques for the study of excited states. This list is not intended to be exhaustive. Papers in the traditional areas of optical spectroscopy (absorption, MCD, luminescence, Raman scattering) are welcome. Papers on applications (phosphors, scintillators, electro- and cathodo-luminescence, radiography, bioimaging, solar energy, energy conversion, etc.) are also welcome if they present results of scientific, rather than only technological interest. However, papers containing purely theoretical results, not related to phenomena in the excited states, as well as papers using luminescence spectroscopy to perform routine analytical chemistry or biochemistry procedures, are outside the scope of the journal. Some exceptions will be possible at the discretion of the editors.