Fluorescence based cadmium detection by protein-assisted synthesis of quantum dots

IF 3.6 3区 物理与天体物理 Q2 OPTICS Journal of Luminescence Pub Date : 2025-06-01 Epub Date: 2025-03-06 DOI:10.1016/j.jlumin.2025.121176
Małgorzata Misiak, Klaudia Jamicka, Artur Bednarkiewicz
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Abstract

The development of an accessible and cost-effective method for heavy metal ions detection holds immense potential for addressing challenges related to detection of contamination in the context of environmental and public health issues. Here, we present an inexpensive and facile method to detect cadmium ions, utilizing bio-assisted synthesis of Cd-containing fluorescent quantum dots. The synthesis is mediated by proteins, which serve as both templates and stabilizers during the formation of the nanoparticles, and enable the control of their size and thus their optical properties. The proposed method demonstrated a detection limit of 0.2 μmol/mL for cadmium ions in water. These studies represent the first attempt at utilizing this approach for selective detection of cadmium ions, paving the way for further innovative solutions in affordable heavy metal ions sensing. The findings may stimulate further investigations of alternative applications of material formation techniques, potentially leading to development of novel applications beyond traditional realms.
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蛋白质辅助合成量子点荧光检测镉
开发一种可获得和具有成本效益的重金属离子检测方法,对于解决在环境和公共卫生问题背景下与检测污染有关的挑战具有巨大潜力。在这里,我们提出了一种廉价和简便的方法来检测镉离子,利用生物辅助合成含镉荧光量子点。合成是由蛋白质介导的,在纳米颗粒形成过程中,蛋白质既是模板又是稳定剂,可以控制纳米颗粒的大小,从而控制其光学性质。该方法对水中镉离子的检出限为0.2 μmol/mL。这些研究代表了利用这种方法选择性检测镉离子的第一次尝试,为在负担得起的重金属离子传感方面进一步创新解决方案铺平了道路。这一发现可能会激发对材料形成技术替代应用的进一步研究,潜在地导致超越传统领域的新应用的发展。
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来源期刊
Journal of Luminescence
Journal of Luminescence 物理-光学
CiteScore
6.70
自引率
13.90%
发文量
850
审稿时长
3.8 months
期刊介绍: The purpose of the Journal of Luminescence is to provide a means of communication between scientists in different disciplines who share a common interest in the electronic excited states of molecular, ionic and covalent systems, whether crystalline, amorphous, or liquid. We invite original papers and reviews on such subjects as: exciton and polariton dynamics, dynamics of localized excited states, energy and charge transport in ordered and disordered systems, radiative and non-radiative recombination, relaxation processes, vibronic interactions in electronic excited states, photochemistry in condensed systems, excited state resonance, double resonance, spin dynamics, selective excitation spectroscopy, hole burning, coherent processes in excited states, (e.g. coherent optical transients, photon echoes, transient gratings), multiphoton processes, optical bistability, photochromism, and new techniques for the study of excited states. This list is not intended to be exhaustive. Papers in the traditional areas of optical spectroscopy (absorption, MCD, luminescence, Raman scattering) are welcome. Papers on applications (phosphors, scintillators, electro- and cathodo-luminescence, radiography, bioimaging, solar energy, energy conversion, etc.) are also welcome if they present results of scientific, rather than only technological interest. However, papers containing purely theoretical results, not related to phenomena in the excited states, as well as papers using luminescence spectroscopy to perform routine analytical chemistry or biochemistry procedures, are outside the scope of the journal. Some exceptions will be possible at the discretion of the editors.
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