Response Surface Optimisation of Carbon Dioxide Adsorption Onto Palm Shell Activated Carbon Functionalised With Natural Amino Acids

Abstract

Amino acids have shown promising results for carbon dioxide (CO₂) capture when functionalised on solid materials; however, the functionalisation often relies on commercial synthetic amino acids. This study investigated the optimal CO₂ adsorption performance of amino acid–functionalised material synthesised from palm shell–based activated carbon and natural amino acids, specifically egg white (EW) solution, in a continuous adsorption column. The process conditions of the column were optimised using response surface methodology. Four parameters, namely, the gas flow rate, adsorption temperature, CO₂ concentration and EW concentration in the impregnation solution, were identified as significantly affecting CO₂ adsorption performance. Good agreements were obtained between the predicted and experimental data, with the coefficients of determination ranging from 0.9639 to 0.9784. A maximum CO₂ adsorption capacity of 1.1793 mmol/g was achieved under optimal process conditions: a gas flow rate of 200 mL/min, an adsorption temperature of 25°C, a CO₂ concentration of 25 vol.%, and an EW concentration of 15 wt.%. The validation results further confirmed the reliability of the developed model equation in predicting the maximum CO₂ adsorption capacity at a fixed 15 vol.% CO₂ concentration, with low estimation error. The comparable results obtained using EW waste in this study represent a significant finding in the potential for waste valorisation, aligning with Sustainable Development Goal (SDG) 12 of the United Nations Sustainable Development Goals, as well as contributing to climate action as outlined in SDG 13.